Group IV zwitterion ansa metallocene (ZAM) catalysts for .alpha.

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 90, 526159, 526160, 502117, 502152, 556 7, 556 53, C08F 444

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active

059395036

ABSTRACT:
Single component metallocene catalysts for .alpha.-olefin polymerization are disclosed. Prior art cation metallocene catalysts have required a separate anion co-catalyst like methyl aluminoxane (MAO). However, because the inventive zwitterion ansa metallocene (ZAM) catalysts have a "built-in" anion co-catalyst functionality, the need for a separate anion co-catalyst is eliminated.

REFERENCES:
patent: 5272236 (1993-12-01), Lai et al.
patent: 5278272 (1994-01-01), Lai et al.
patent: 5347024 (1994-09-01), Nickias et al.
patent: 5384299 (1995-01-01), Turner et al.
patent: 5459117 (1995-10-01), Ewen et al.
patent: 5470993 (1995-11-01), Devore et al.
patent: 5486632 (1996-01-01), Devore et al.
patent: 5792819 (1998-08-01), Erker et al.
Rufanov et al., "Hetero-ansa-metallocenes: I. Synthesis of the novel 525 (1996) pp. 287-289.
Chang, R., Chemistry, McGraw-Hill, 1988, p. 497.
Reetz, et al., "Preparation and Catalytic Activity of Boron-Substituted Zirconocenes," CHIMIA vol. 49, Nr. 12, pp. 501-503 (1995).
Sun, et al., "Intramolecular Ion-Ion Interactions in Zwitterionic Metallocene Olefin Polymerization Catalysts Derived from `Tucked-In` Catalyst Precursors and the Highly Electrophilic Boranes XB (C.sub.6 F.sub.5).sub.2 (X.dbd.H, C.sub.6 F.sub.5)," J. Am. Chem. Soc. 119:5132-43 (1997).
Rodriguez, et al., "Synthesis, Structural Characterization, and Reactivity of Zirconium Complexes Containing Trimethylenemethane-Based Ligands," J. Am. Chem. Soc. 119:343-52, (1997).
Kreuder, et al., "Early metal Carborane Chemistry. Generation and Reactivity of (C.sub.5 Me.sub.5) (.eta..sup.5 -C.sub.2 B.sub.9 H.sub.11)TiMe," Organometallics 14:2993-3001 (1995).
Rufanov, et al., "Hetero-ansa-metallocenes: I. Synthesis of the novel 525:287-89 (1996).
Bochmann, et al., "Anionic and Zwitterionic Metallocene Complexes derived from Novel Boratocyclopentadienyl Ligands," J. Chem. Soc., Chem. Commun., pp. 2081-82 (1995).
Woo, et al., "Combined Static and Dynamic Density Functional Study of the Ti(IV) Constrained Geometry Catalyst (CpSiH.sub.2 NH)TiR.sup.+. 1. Resting States and Chain Propagation," J. Am. Chem. Soc. 118:13021-30 (1996). -NCMe.sub.3)}(PMe.sub.3)ScH!.sub.2 : A Unique Example of a Single-Component .alpha.-Olefin Polymerization Catalyst," Organometallics 9:867-69 (1990).

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