Group 4, metal-conjugated diene metallocyclopentene complexes, a

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526127, 526133, 526134, 526160, 526170, 526352, 502103, 502117, 502152, 556 7, 556 11, 556 22, 556 52, C08F 4643

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055390684

ABSTRACT:
Novel Group 4 metal complexes containing one and only one cyclic delocalized, anionic, .pi.-bonded group wherein the metal is in the +4 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes and a conjugated diene divalent anionic ligand group; catalytic derivatives of such complexes including novel zwiterionic complexes; and the use thereof as catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.

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