Granular detergent compositions containing deflocculating polyme

Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – For cleaning a specific substrate or removing a specific...

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Details

510351, 510352, 510452, 510453, 510475, 510476, C11D 337, C11D 1102

Patent

active

057234272

ABSTRACT:
The present invention provides for concentrated, granular detergent compositions comprising a mixture of:
a) from about 15 to about 50% by weight of a surfactant;
b) at least one detergent builder;
c) from about 0.01 to about 7.5% by weight of a deflocculating polymer composition containing polymer chains of the structure P-QR, wherein P represents a polymer chain segment of a hydrophilic polymer, and QR represents a hydrophobic end-cap group wherein R is an organic hydrophobic radical containing from about 4 to 28 carbon atoms, and Q is selected from the group consisting of O, CO.sub.2, S, SO, SO.sub.2, NR', PO.sub.4 R', PO.sub.3 R', Si OR'R", Si R'R", CR'OH, CR'R" and CR'OR" wherein R' and R" are each hydrogen, an alkyl group containing from 1 to 4 carbon atoms or an aryl group; and
d) water.
The addition of the deflocculating polymer to a crutcher slurry prior to drying the slurry retards the propensity of the lamellar surfactant droplets dispersed in the slurry to flocculate, particularly where the droplets occupy a higher volume ratio as the result of high concentrations of surfactant present in the detergent.
The resultant slurry exhibits a significantly reduced viscosity which renders it more readily pumpable in a spray drying process.

REFERENCES:
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patent: 3922230 (1975-11-01), Lamberti et al.
patent: 5147576 (1992-09-01), Montague et al.
patent: 5489397 (1996-02-01), Bainbridge
patent: 5599784 (1997-02-01), Bainbridge
patent: 5602092 (1997-02-01), Repinec, Jr. et al.
PCT Search Report for PCT/US95/15591, May 3, 1996.
Derwent abstract accession No. 89-372253/51, for EP 346995, published Dec. 20, 1989, 1995.
Chemical Abstracts, vol. 101, No. 20, 12 Nov. 1984, Columbus, OH, US; abstract no. 173478u, ABE: "Sequestering Agents", p. 123, col. 1; XP002000806 & JP,A,59 091 184 (Yoshio Adeka Argus Chemical Co. Ltd) 25 May 1984.
Database WPI, Section Ch, Week 9005, Derwent Pubications Ltd., London, GB; Class B01, AN 90-033259 XP002000807 "Dispersant for use in Detergent . . . ", & JP,A,01 310 730 (Kao Corp), 14 Dec. 1989.

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