Grafted microporous separator for electrochemical generator and

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Separator – retainer – spacer or materials for use therewith

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429194, 429253, H01M 216

Patent

active

055784003

ABSTRACT:
A separator for an electrochemical generator is constituted by a microporous polyolefin film grafted with at least one monomer selected from diethyleneglycol dimethacrylate, furfuryl acrylate and a diethyleneglycol dimethacrylate/acrylic acid mixture. In a process for the production of a separator of this kind grafting of the monomer is carried out in three stages:
irradiation of the film,
if required, storage of the irradiated film,
immersion of the irradiated film in the grafting solution comprising the monomer, a solvent, and at least one additive. The separator may be used in an electrochemical generator with either an aqueous or nonaqueous electrolyte where the salt concentration is between 1M and 2M.

REFERENCES:
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patent: 4539277 (1985-09-01), Ishigaki et al.
patent: 4629540 (1986-12-01), Geniees et al.
patent: 4705636 (1987-11-01), Small et al.
patent: 5270137 (1993-12-01), Kubota
JP 62258711 dated Nov. 11, 1987 (Asahi Chemical Ind.).
French Search Report FR 9209900.

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