Graft copolymers containing ionomer units

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525217, 525222, 525241, 524515, 524528, C08F25700, C08F25702, C08F25900, C08F25902

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active

060605634

ABSTRACT:
Graft copolymers having cationic units pendant to the backbone chain are disclosed. These polymers are prepared by reacting a polymer containing halogenated paramethylstyrene units in the chain, e.g., a brominated copolymer of isobutylene and para-methylstyrene, with an anionically polymerized polymer made using an organolithium initiator compound having the formula R.sub.1 R.sub.2 Z R.sub.3 --Li where R.sub.1 and R.sub.2 are alkyl radicals, R.sub.3 is a direct link or an organic radical and Z is nitrogen or phosphorous. Reaction of the anionically polymerized polymer having an R.sub.1 R.sub.2 Z R.sub.3 --end group with the halogenated polymer leads to graft polymers coupled by a quaternary ammonium or phosphonium groups.

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3-Dimethylaminiopropyl-Lithium-An Analytical and Kinetic Investigation of a New Initiator System for Polymer Synthesis, C.D. Eisenbach, et al., European Polymer Journal, vol. 11, p 699-704 (1975).

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