Graft copolymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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Details

C525S353000, C525S535000, C525S536000, C521S027000, C521S030000, C521S033000, C521S034000, C521S037000

Reexamination Certificate

active

11030576

ABSTRACT:
This invention relates to methods of making graft copolymers, and articles having such graft copolymers. The methods may provide better control than in radicalization or photoinitiated polymerization techniques. For example, a graft copolymer can be prepared by reacting an alkoxide ion with a polymer. The alkoxide, in turn, can be provided by any suitable technique, for example, by reacting an alcohol with a base. In some embodiments of the invention, the graft copolymers may be a normally hydrophobic polymer, such as a polysulfone, that has been made more hydrophilic due to the attachment of hydrophilic side groups such as polyethylene glycol or polypropylene glycol. The copolymers of the invention have many uses, for example, in films or porous membranes.

REFERENCES:
patent: 4244817 (1981-01-01), Yaginuma
patent: 5076925 (1991-12-01), Roesink et al.
patent: 5171264 (1992-12-01), Merrill
patent: 6150459 (2000-11-01), Mayes et al.
patent: 6172180 (2001-01-01), Hancock et al.
patent: 6207749 (2001-03-01), Mayes et al.
patent: 6413621 (2002-07-01), Mayes et al.
patent: 2002/0147282 (2002-10-01), Mayes et al.
patent: 2002/0155311 (2002-10-01), Mayes et al.
International Search Report in PCT Application No. PCT/US03/20968, Int'l Filing Date, Mar. 7, 2003.
Mika, A.M., “A new class of polyelectrolyte-filled microfiltration membranes with environmentally controlled porosity,” Journal of Membrane Science, vol. 108 (1995), pp. 37-56.
Iwata, Hiroo, et al., “Preparation and properties of novel environment-sensitive membranes prepared by graft polymerization onto a porous membrane,” Journal of Membrane Science, vol. 38, (1988) pp. 185-199.
Daley, W.H. et al., “Grafting of Vinyl Polymers to Carboxylated Poly(arylene ether sulfone) Utilizing Barton Ester Intermediates and Nitroxide Mediation,” Polymer 41 (2000), pp. 5063-5071.
Hancock, L. et al., “Hydrophilic Semipermeable Membranes Fabricated with Poly(ethylene oxide)-polysulfone Block Copolymer,” Biomaterials 21 (2000), pp. 725-733.
Hancock, L. et al., “Phase Inversion Membranes with an Organized Surface Structure from Mixtures of Polysulfone-Poly (ethylene oxide) Block Copolymers,” Journal of Applied Polymer Science (1977), 66:1353-1358.
Higuchi, A. et al., “Chemically Modified Polysulfone Hollow Fibers with Vinylpyrrolidone Having Improved Blood Compatibility,” Biomaterials 23 (2002) pp. 2659-2666.
Kaeselev, B. et al., “Photoinduced Grafting of Ultrafiltration Membranes: Comparison of Poly(ether sulfone) and Poly(sulfone), ” Journal of Membrane Science (2001) 194:245-261.
Kim, H. et al., “The Transport Properties of CO2and CH4for Chemically Modified Polysulfones,” Journal of Applied Polymer Science (2000) 76:391-400.
Kotzelski, J. et al., “Kinetics of Bonded Invertase: Asymmetric Polysulfone Membranes,” Journal of Membrane Science (1996) 114:201-214.
Song, Y. et al., “Surface Modification of Polysulfone Membranes by Low-Temperature Plasma-Graft Poly(ethylene glycol) onto Polysulfone Membranes,” Journal of Applied Polymer Science (2000) 78:979-985.
Ting, Y. et al., “Preparation of Polysulfone/Poly(ethylene oxide) Block Copolymers,” Macromolecules (1996) 29:7619-7621.
Ulbricht, M. et al., “Novel Photochemical Surface Functionalization of Polysulfone Ultrafiltration Membranes for Covalent Immobilization of Biomolecules,” Journal of Membrane Science (1996) 120:239-259.
Yoshikawa, M. et al., “Modified Polysulfone Membranes. III. Pervaporation Seperation of Benzene-Cyclohexane Mixtures through Carboxylated Polysulfone Membranes,” Journal of Applied Polymer Science (1999) 74:407-412.
Zhu, S. et al., “Synthesis of Aromatic Polyethersulfone-Based Graft Copolyacrylates via ATRP Catalyzed by FeCI2/Isophthalic Acid,” Journal of Polymer Science: Part A: Polymer Chemistry (2001) 39:2943-2950.

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