Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From heterocyclic reactant containing as ring atoms oxygen,...
Patent
1978-11-09
1980-03-25
Nielsen, Earl A.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From heterocyclic reactant containing as ring atoms oxygen,...
526273, 528 88, 528 95, 528393, 528409, 528419, C08G 6508
Patent
active
041951670
ABSTRACT:
Polymers which comprise polymer chains along which the proportion of mer units provided by a first heterocyclic monomer gradually increases in a given chain length as the proportion of mer units provided by a second heterocyclic monomer gradually decreases along said chain length. In one form, the portions of the polymers adjacent one end of the given chain lengths have about 100% of mer units provided by the first monomer and about 0% of mer units provided by the second monomer and the portions adjacent the other end of the given chain lengths have about 0% of mer units provided by the first monomer and about 100% of mer units provided by the second monomer. Additional forms of polymers are disclosed.
Process for producing such polymers comprising introducing at least one primarily polymerizable feed composition comprising at least one of the monomers described above from at least one primary feed source to a polymerization zone, the primary polymerizable feed composition continually varying in compositional content of the monomers therein during said continuous introduction; simultaneously adding to primary feed source at least one different secondary polymerizable feed composition comprising at least one different monomer as described above from at least one secondary feed source so as to continually change the compositional content of the polymerizable monomers in the primary polymerizable feed composition in the primary feed source; and continuously polymerizing the primary polymerizable feed composition introduced to the polymerization zone until desired polymerization has been achieved.
The method of this invention is particularly useful in controlling the ratio of primary to secondary hydroxyl terminal groups in the product.
REFERENCES:
patent: 3029216 (1962-04-01), Bailey et al.
patent: 3682865 (1972-08-01), Jenkins et al.
patent: 3804881 (1974-04-01), Bassett et al.
patent: 3839293 (1974-10-01), Knopf et al.
Hoy Kenneth L.
Knopf Robert J.
Nielsen Earl A.
Schoenberg Franklyn
Union Carbide Corporation
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