Golf ball

Details Golf ball Golf ball

2000-06-13

2002-03-26

Sewell, Paul T. (Department: 3711)

Games using tangible projectile

Golf

Ball

C473S351000, C473S365000

Reexamination Certificate

active

06361455

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to a golf ball having excellent spin performance. More particularly, it relates to a golf ball having excellent flyer resistance when executing a shot out of the rough, as well as possessing excellent cut resistance and high rebound characteristics.
BACKGROUND OF THE INVENTION
Solid golf balls, such as a two-piece golf ball or a three-piece golf ball, and thread wound golf balls have been used for rounds of golf. The solid golf ball consists of a solid core of integrally molded rubber material comprising polybutadiene as a main component and a cover of thermoplastic resin (e.g. ionomer resin) covering on the solid core. The thread wound golf ball consists of a solid or liquid center, a thread rubber layer formed by winding thread rubber in a stretched state around the center, and a cover of ionomer resin or balata etc. covering the thread wound layer.
The golf ball is often hit in tall grass or rough during normal play. When hit from the rough, a phenomenon called a flyer often occurs, that is, the amount of backspin is small and the ball trajectory is high due to the presence of grass between the golf club face and the golf ball when hitting from the rough. This phenomenon is one of the reasons why it is difficult to control approach shots. The phenomenon occurs regardless of whether a solid golf ball or a thread wound golf ball is utilized, and many golf players are troubled by such a phenomenon.
It has been apparent from studying golf balls utilizing every type of cover that the flyer occurs more frequently when hitting the golf ball using an ionomer resin cover as compared to using a balata cover. The ionomer resin cover has a high elastic modulus and excellent rebound characteristics, but the resulting golf ball formed by the cover has a small spin amount and poor controllability.
On the other hand, in case of a golf ball using a balata cover, although a flyer is less likely to occur and the controllability of the spin is excellent, the rebound characteristics of the cover material and the cut resistance is poor.
OBJECTS OF THE INVENTION
A main object of the present invention is to provide a golf ball having excellent spin performance and excellent flyer resistance while executing a golf shot from the rough and also having excellent cut resistance and high rebound characteristics.
According to the present invention, the object described above has been accomplished by adjusting the shear modulus (G), the Young's modulus (E) and the ratio of E/G to within specified ranges, thereby providing a golf ball having excellent spin performance and excellent flyer resistance when executing a golf shot from the rough and also having excellent cut resistance and high rebound characteristics.
SUMMARY OF THE INVENTION
The present invention provides a golf ball comprising a core and a cover covering the core,
wherein the cover has a shear modulus (G) of 3 to 100 MPa, a Young's modulus (E) of 9 to 400 MPa, and a ratio (E/G) of 2.4 to 3.0.
The present inventors have studied the reason why the flyer shot occurs and have found that the spin amount is sufficiently maintained and the flyer shot is less likely to occur as a relation between the shear modulus (G) and a Young's modulus (E) of the cover of the golf ball is close to the formula:
E=3G
The statement of E=3G, which is generally known, shows that a polymer chain has a three-dimensional network structure because it has a crosslink or bond similar thereto.
The ionomer resin, which has been typically used of the cover of the golf ball, does not have a chemical, three-dimensional network structure and the value of E/G is less than 2.4 in most cases. It has been shown that an ionomer resin experiences difficulty in recovering its original shape because the elastic modulus in the direction of shearing stress is small, and plastic deformation occurs by applying an outer force in this direction. If the value E/G is smaller than 2.4 at the time of hitting of the golf ball, that is, when the shearing stress is applied to the golf ball, the spin amount is small and a flyer type golf shot is likely to occur.
On the other hand, if the cover material has a chemical three-dimensional network structure, the plastic deformation does not occur by deforming in the direction of the shearing stress and it generally recovers its original shape. Therefore when the relationship between E and G is close to the formula: E=3G, the spin amount is large and the possibility of a flyer type shot is substantially reduced. In addition, since the cover material is crosslinked, the cut resistance is excellent.
There is a cover material, which has suspected crosslinking portion (a frozen phase or crystalline phase), shows the behavior as it is three-dimensionally crosslinked and has the E/G value of not less than 2.4, in thermoplastic resin other than rubber or thermosetting resin.
DETAILED DESCRIPTION OF THE INVENTION
The golf ball of the present invention is composed of a core and a cover formed on the core. The golf ball of the present invention may be either solid golf ball such as two-piece solid golf ball or thread wound golf ball. The core for solid golf ball (solid core) may be the same one that has been conventionally used, and may be obtained by mixing a rubber composition using a mixer such as a mixing roll, and then vulcanizing (crosslinking) or press-molding the rubber composition in a given mold into a spherical form. The rubber composition comprises 10 to 60 parts by weight of a vulcanizing agent (crosslinking agent), for example, (&agr;, &bgr;-unsaturated carboxylic acid (such as acrylic acid, methacrylic acid, etc.) or a metal salt thereof, or a functional monomer such as trimethylolpropane trimethacrylate, or a combination thereof; 0.5 to 5 parts by weight of organic peroxides such as dicumyl peroxide, etc.; 10 to 30 parts by weight of filler such as zinc oxide, barium sulfate and the like; optionally antioxidant, based on 100 parts by weight of a base rubber such as polybutadiene. The vulcanization may be conducted, for example, by press molding in a mold at 140 to 170° C. for 10 to 40 minutes.
The core for thread wound golf ball (thread wound core) comprises a center and a thread rubber layer formed by winding thread rubber in a stretched state around the center, wherein the center may be either liquid center or solid center formed from rubber composition. The thread rubber can be the same one that has been conventionally used for the thread rubber layer of the thread wound golf ball. For example, the thread rubber can be obtained by vulcanizing a rubber composition prepared by formulating sulfur, a vulcanization aid, a vulcanization accelerator, an antioxidant and the like to a natural rubber or a blend rubber of the natural rubber and a synthetic polyisoprene. The examples of solid core and thread wound core are only for purpose of illustration, and are not to be construed to limit thereto.
In the golf ball of the present invention, the core has a diameter of 34.8 to 41.8 mm, preferably 36.0 to 41.0 mm. When the diameter of the core is smaller than 34.8 mm, the cover is too thick, and the volume content of the cover is large and the rebound characteristics are degraded. On the other hand, when the diameter of the center is larger than 41.8 mm, the cover is too thin, and the durability is degraded.
The cover is then covered on the core. It is required that the cover of the golf ball of the present invention have a Young's modulus (E) of 9 to 400 MPa, a shear modulus (G) of 3 to 100 MPa and a ratio (E/G) of 2.4 to 3.0.
It is desired that the Young's modulus (E) of the cover have the lower limit of preferably not less than 20 MPa, more preferably not less than 40 MPa, most preferably not less than 50 MPa. It is desired that the Young's modulus (E) of the cover have the upper limit of preferably not more than 300 MPa, more preferably not more than 270 MPa. It is desired that the shear modulus (G) of the cover have the lower limit of preferably not le

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