Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Reexamination Certificate
2000-04-06
2001-02-13
Barts, Samuel (Department: 1621)
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
C568S871000, C568S872000
Reexamination Certificate
active
06187973
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to the removal of impurities such as aldehydes from aqueous ethylene glycol solutions by treatment with bisulfite treated strong base anion exchange resin.
2. Description of the Prior Art
Ethylene glycol is a very important chemical of commerce which is usually prepared by reaction of ethylene oxide and water. A problem which has existed is that during the preparation procedure impurities such as aldehydes are formed which are difficult to separate from ethylene glycol and which cause problems in applications where very high purity is required, for example in the manufacture of fibers.
Both physical methods as well as chemical methods have been devised for the separation of aldehydes from ethylene glycol. U.S. Pat. No. 4,349,417, for example, proposes distillation in the presence of a alkali metal compounds as a purification procedure. This patent also refers to German Ausligeschrift No. 2,558,039 as teaching ethylene glycol purification using an ion exchange resin.
U.S. Pat. No. 4,358,625 teaches reducing oxygen—containing impurities by treatment with alkali metal borohydride.
U.S. Pat. No. 3,904,656 teaches treating a purge stream from an ethylene oxide stripper with a cation exchange resin Amberlyst A-15, an anion exchange resin Amberlyst A-21, and a carbon bed prior to recycle.
U.S. Pat. No. 4,560,813 teaches hydrolysis of alkylene oxide using a methylate anion—containing natural and recovery of the methylate anion by contact with a solid such as anion exchange resin.
U.S. Pat. No. 5,440,058 mentions treatment of aqueous streams with weakly basic ion exchange resins which have been reacted with a bisulfite salt in order to remove aldehyde impurities.
Despite the efforts of prior workers, further improvements in the removal of impurities such as aldehydes from aqueous ethylene glycol streams is important and desirable.
REFERENCES:
patent: 3904656 (1975-09-01), Broz
patent: 4349417 (1982-09-01), Rebsdat et al.
patent: 4358625 (1982-11-01), Paggini et al.
patent: 4560813 (1985-12-01), Collier
patent: 5440058 (1995-08-01), Hoffman et al.
patent: 2558039 (1976-07-01), None
Database CAPLUS on STN, Acc. No. 1995:220402, Schmitt et al, ‘Purification of ethylene glycol using anion exchange resins.’ CA 1330350 A1 (abstract), 1995.
Barts Samuel
Davis Brian J.
Long William C.
Scientific Design Company, Inc.
LandOfFree
Glycol purification does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Glycol purification, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Glycol purification will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2602714