Glass compositions

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501 17, 501 21, 501 66, 501 67, 428426, C03C 100

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active

056058691

ABSTRACT:
An on-glaze low expansion glass flux composition suitable for coating onto a glazed surface which is essentially free from lead and cadmium and comprises, in mole percent, SiO.sub.2 : 35 to 75%, Bi.sub.2 O.sub.3 : 4 to 12%, Al.sub.2 O.sub.3 : 2 to 12%, B.sub.2 O.sub.3 : 18 to 35%, at least one of Li.sub.2 O, Na.sub.2 O, K.sub.2 O : 0 to 12% (in total), and certain other optional ingredients with the provisos that BaO is not contained in an amount of more than 2 mole percent, the total amount of Bi.sub.2 O.sub.3 +B.sub.2 O.sub.3 +Li.sub.2 O,Na.sub.2 O and K.sub.2 O is in the range of from 25 to 45 mole percent, the total amount of Li.sub.2 O, Na.sub.2 O and K.sub.2 O is in the range of up to 10 percent by weight except when the only alkali metal oxide present is Li.sub.2 O, and the composition has a coefficient of thermal expansion in the range of from 4.0 to 7.0.times.10.sup.-6 /.degree.C. These glass flux compositions are of particular use in the preparation of enamel compositions for the decoration of low-expansion porcelain ware.

REFERENCES:
patent: 4282035 (1981-08-01), Nigrin
patent: 4446241 (1984-05-01), Francel et al.
patent: 4554258 (1985-11-01), Francel
patent: 4590171 (1986-05-01), Nigrin
patent: 4892847 (1990-01-01), Reinherz
patent: 4970178 (1990-11-01), Klimas et al.
patent: 5200369 (1993-04-01), Clifford et al.
patent: 5244848 (1993-09-01), Clifford et al.
patent: 5308803 (1994-05-01), Clifford et al.
Chemical Abstracts, vol. 110, No. 6, 20 Mar. 1989.

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