Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And additional al or si containing component
Reexamination Certificate
2004-12-16
2008-11-18
Wood, Elizabeth D (Department: 1793)
Catalyst, solid sorbent, or support therefor: product or process
Zeolite or clay, including gallium analogs
And additional al or si containing component
C502S060000, C502S073000, C502S065000, C502S069000
Reexamination Certificate
active
07452839
ABSTRACT:
The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a rare earth component which enhances the cracking activity of the cracking catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The rare earth component preferably includes cerium which enhances the sulfur reduction activity of the catalyst. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.
REFERENCES:
patent: 3293192 (1966-12-01), Maher et al.
patent: 3354078 (1967-11-01), Miale et al.
patent: 3402996 (1968-09-01), Maher et al.
patent: 3607043 (1971-09-01), McDaniel et al.
patent: 3676368 (1972-07-01), Scherzer et al.
patent: 3711422 (1973-01-01), Johnson et al.
patent: 3977963 (1976-08-01), Readal et al.
patent: 4115249 (1978-09-01), Blanton et al.
patent: 4153534 (1979-05-01), Vasalos
patent: 4153535 (1979-05-01), Vasalos et al.
patent: 4340465 (1982-07-01), Miller et al.
patent: 4440871 (1984-04-01), Lok et al.
patent: 4500651 (1985-02-01), Lok et al.
patent: 4544143 (1985-10-01), Cooper et al.
patent: 4549956 (1985-10-01), Chu
patent: 4567029 (1986-01-01), Wilson et al.
patent: 4683217 (1987-07-01), Lok et al.
patent: 4686092 (1987-08-01), Lok et al.
patent: 4744970 (1988-05-01), Lok et al.
patent: 4758419 (1988-07-01), Lok et al.
patent: 4790982 (1988-12-01), Yoo et al.
patent: 4793984 (1988-12-01), Lok et al.
patent: 4935216 (1990-06-01), Lok et al.
patent: 4957718 (1990-09-01), Yoo et al.
patent: 4957892 (1990-09-01), Yoo et al.
patent: 4963520 (1990-10-01), Yoo et al.
patent: 5098684 (1992-03-01), Kresge et al.
patent: 5102643 (1992-04-01), Kresge et al.
patent: 5198203 (1993-03-01), Kresge et al.
patent: 5376608 (1994-12-01), Wormsbecher et al.
patent: 5407878 (1995-04-01), Kim
patent: 5525210 (1996-06-01), Wormsbecher et al.
patent: 5705729 (1998-01-01), Huang
patent: 6974787 (2005-12-01), Chester et al.
patent: 0 159 624 (1991-12-01), None
Venuto and Habib, Fluid Catalytic Crackling with Zeolite Catalysts, Marcel Dekker, New York 1979, ISBN 0-8247-6870-1, pp. 32-37.
Richard F. Wormsbecher, Alan W. Peters, and James M. Maselli, “Vanadium Poisoning of Cracking Catalysts: Mechanism of Poisoning and Design of Vanadium Tolerant Catalyst System”, Journal of Catalyst, vol. 100, pp. 130-137 (1986).
Occelli, M.L., “Metal Resistant Fluid Cracking Catalysts”, ACS Symposium Series, Ch 21, pp. 343-362 (1990).
“Shape Selective Catalysis in Industrial Applications”; Chen et al., Marcel Dekker Inc., New York 1969, ISBN 0-8247-7856-1, pp. 7-38.
J ournal of Catalysis, vol. 67, pp. 218-222 (1981) by Frilette et al.
Journal of Catalysis, vol. 4, pp. 527-529 (1965); vol. 6, pp. 278-287 (1966); and vol. 61, pp. 390-396 (1980).
Scherzer, “Octane Enhancing Zeolitic FCC Catalysts”, Marcel Dekker, New York, 1990, ISBN 0-8247-8399-9, pp. 165-182.
Intercat, Refining Developments, “Additives Improve FCC Process”, Hydrocarbon Processing, Nov. 1991, pp. 59-66, by A.S. Krishna, C.R. Hsieh, A.R. English, T.A. Pecararo and C.W. Kuehler, Chevron Research and Technology Company, Richmond, CA.
“Fluid Catalytic Cracking Handbook”, Sadeghbeigi, Gulf Publishing, Houston, Texas, ISBN 0-88415-290-1, Ch. 3, pp. 79 and 88-91, no date.
Cheng Wu-Cheng
Purnell Scott Kevin
Roberie Terry G.
Timken Hye Kyung Cho
Zhao Xinjin
Artale Beverly J.
Cross Charles A.
W. R. Grace & Co.,-Conn.
Wood Elizabeth D
LandOfFree
Gasoline sulfur reduction in fluid catalytic cracking does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Gasoline sulfur reduction in fluid catalytic cracking, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Gasoline sulfur reduction in fluid catalytic cracking will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-4029217