Gasohol production from thermochemical conversion of biomass to

Fuel and related compositions – Liquid fuels – Aluminum or heavy metal – other than lead – containing

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44 53, 44 68, 568920, 568921, 568922, C10L 118

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045239282

ABSTRACT:
Disclosed is a method for thermochemically converting a carbohydrate material into ethanol wherein the carbohydrate material and a metal salt are reacted at elevated temperature to form an intermediate carbohydrate complex salt and/or a lactate metal salt which then is pyrolyzed in the presence of water into ethanol. Preferred carbohydrate materials for the process are various sugars and the metal salt preferably is a metal oxide, hydroxide, or carbonate. The intermediate complex and/or lactate salt may be separated from its aqueous reaction mixture prior to its pyrolysis to reduce the ultimate separation of ethanol from water. Alternatively, the metal of the metal salt may be one whose carbonate decomposes to metal oxide and carbon dioxide during the pyrolysis step of the process to generate said metal salt in situ.

REFERENCES:
patent: 1496810 (1924-06-01), Keyes
patent: 1527504 (1925-02-01), Backhaus
patent: 1578201 (1926-03-01), Midgley, Jr.
patent: 2177557 (1939-10-01), Bergstrom et al.
patent: 2382889 (1945-08-01), Lock
Hanriot, "Sur la Decomposition Pyrogenee des Acides de la Serie Grasse", Nouv. Ser., T. XLV, Societe Chimique, pp. 79-81, (1886).
Fischer Schrader and Wolter, "Uber die Entkarboxylierung der Milschaure", Gesamm. Abh. Kenntni Kohle, 6, 99-107, 1923.

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