Gas purification

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon dioxide or hydrogen sulfide component

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423236, 423571, 423573G, C01B 1704

Patent

active

039668762

ABSTRACT:
Gas purification processes for removing hydrogen sulphide (H.sub.2 S) from a foul gas stream, such as coal carbonization gases, involving a circulating liquid reagent in which the H.sub.2 S is absorbed and converted to sulphur which is recovered and the reagent regenerated and recycled exhibit progressive deterioration of the circulating reagent due to contamination by process by-products. The invention provides a method of decontaminating such a circulating reagent by subjecting a bled-off sidestream to high temperature hydrolysis, so producing gaseous products recyclable to the foul gas stream. Solid products may also be produced which may be recycled to the reagent, perhaps after high-temperature reduction.

REFERENCES:
patent: 1542971 (1925-06-01), Sperr et al.
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patent: 1852160 (1932-04-01), Hansen
patent: 1932819 (1933-10-01), Hansen
patent: 1961255 (1934-06-01), Sperr
patent: 3086838 (1963-04-01), Giammarco
patent: 3558272 (1971-01-01), Urban
patent: 3878289 (1975-04-01), Beavon
patent: 3887682 (1975-06-01), Kumata et al.

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