Gas phase synthesis of bis(trifluoromethyl) disulfide

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing

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C07C14800

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043407625

ABSTRACT:
A method of preparing bis(trifluoromethyl) disulfide, which comprises contacting, in the gaseous state, 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane with activated carbon catalyst at elevated temperature is disclosed.

REFERENCES:
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J. V. Martin, J. Chem. Soc., 2944 (1964), Reaction of Fluoro-olefins with Sulfur.
M. Hauptschein et al., J.A.C.S., 73, 5461-63 (1951), Perfluoro-n-propyl Disulfide & Perfluoro-n-propyl Trisulfide.
E. W. Lawless and L. D. Harman, J. Inorg. & Nuclear Chem., 31, 1541 (1969).
C. T. Tullock and D. D. Coffman, J. Org. Chem., 25, 2016 (1960).
R. E. Banks and R. N. Haszeldine, Advances In Inorganic Chem., 3, 414-416 (1961).

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