Gas phase polymerization employing unsupported catalysts

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526138, 526160, 5263482, 5263484, 5263485, 5263486, 526351, 526352, 526901, 526943, C08F 234

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057445567

ABSTRACT:
A process for the gas-phase polymerization of polymers which allows for the introduction of an unsupported polymerization catalyst system into the gas-phase reactor, wherein the unsupported polymerization catalyst system comprises (i) a non-volatile materials fraction containing a polymerization catalyst; (ii) a solvent fraction which is at least partially miscible with the non-volatile materials fraction and which is sufficiently volatile to allow for the formation of polymerization catalyst particles when the mixture of the solvent fraction and the non-volatile materials fraction is sprayed into the reactor; (iii) a compressed fluid; and (iv) optionally a slowly vaporizing solvent.

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Dixon, et al, "Polymeric Materials Formed by Precipitation with a Compressed Fluid Antisolvent", AIChE Journel, 39, No. 1, 127-139, 1993.

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