Gas conversion using synthesis gas produced hydrogen for catalys

Chemistry: fischer-tropsch processes; or purification or recover – Group viii metal containing catalyst utilized for the...

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518702, 518709, 518700, 518722, 252373, 208 56, 208 59, C07C 2700, C07C 2706, C07C 102, C10G 4500, C10G 6500

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060432888

ABSTRACT:
A gas conversion process in which both hydrocarbons and hydrogen are produced from a synthesis gas feed which comprises a mixture of H.sub.2 and CO, uses hydrogen from a portion of the feed for one or more of (i) hydrocarbon synthesis catalyst rejuvenation and (ii) hydroconversion upgrading of at least a portion of the synthesized hydrocarbons. Hydrogen is produced from a slipstream of the synthesis gas fed into the hydrocarbon synthesis reactor by one or more of (i) physical separation means such as pressure swing adsorption and (ii) chemical means such as a water gas shift reactor. If a shift reactor is used due to insufficient capacity of the synthesis gas generator, physical separation means such as pressure swing adsorption will still be used to separate a pure stream of hydrogen from the shift reactor gas effluent.

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D. M. Bibby, et al. (eds), SYNGAS FOR C.sub.1 -CHEMISTRY. Limits of the Steam Reforming Process, Methane Conversion, pp. 73-78, (Elsevierm, 1988).

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