Gas conversion using hydrogen from syngas gas and hydroconversio

Chemistry: fischer-tropsch processes; or purification or recover – Group viii metal containing catalyst utilized for the...

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518700, 518702, 518703, 518709, 518715, 518722, 252373, 208 56, 208 59, C07C 2700

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active

061471267

ABSTRACT:
A gas conversion process including catalytic hydrocarbon synthesis from a synthesis gas comprising a mixture of H.sub.2 and CO, produces hydrogen from the synthesis gas and upgrades synthesized hydrocarbons by one or more hydroconversion operations which utilize this hydrogen. The hydroconversion also produces a hydrogen rich tail gas which is used in the process for at least one of (i) hydrocarbon synthesis catalyst rejuvenation, (ii) the hydrocarbon synthesis, and (iii) hydrogen production. In one embodiment the tail gas is used to hydrodesulfurize sulfur-containing hydrocarbon liquids recovered from the natural gas used to form the synthesis gas. The hydrogen production is accomplished by physical separation, such as PSA, with or without chemical means such as a water gas shift reaction.

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D. M. Bibby, et al (eds), Syngas for C.sub.1 -Chemistry. Limits of the Steam Reforming Process, Methane Conversion, pp. 73-78, (Elsevier, 1988).

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