Gas chromatography sample injector and apparatus using same

Chemical apparatus and process disinfecting – deodorizing – preser – Analyzer – structured indicator – or manipulative laboratory... – Means for analyzing gas sample

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436161, 436173, 73 2341, 73 2342, 250425, G01N 3002

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active

054726700

ABSTRACT:
The present invention relates to an improved sample injector for use in gas chromatography. The invention also includes a method of injecting a sample onto a chromatographic column, and a method of analyzing a sample using column chromatography and/or mass spectrometry. The improved sample injector features an arrangement to allow a pyrolytic probe to be more easily inserted into the vaporization cavity while permitting the sample to be volatilized in such a way that the sample is more efficiently introduced onto the column. Another feature of the invention is the use of means to reduce the volume of the pyrolysis/vaporization cavity so as to provide efficient throughput of pure sample. Also part of the present invention is a gas chromatograph and gas chromatograph-mass spectrometer which uses the sample injector of the present invention. The present invention includes methods of sample injection and sample analysis using the aforementioned apparatus of the present invention.

REFERENCES:
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patent: 4408125 (1983-10-01), Meuzelaar
patent: 4980131 (1990-12-01), Meuzelaar et al.
patent: 5150601 (1992-09-01), Simeroth et al.
Barbour, William M. "Refinement of Pyrolysis Techniques for Gas Chromatography" J. of G.C., Jul. 1965, pp. 228-231.
Berezkin, V. G. "The Development of Pyrolysis Gas Chromatography." CRC Critical Reviews in Analytical Chemistry, Mar. 1981, pp. 1-25.
Levy, R. L. "Trends and Advances in Design of Pyrolysis Units for Gas Chromotography" J. of G.C., Jul. 1965, pp. 228-231.
Levy, R. L. Pyrolysis Gas Chromatography, pp. 49.varies.85.
Morgan, Stephen L. and Jacques, Christopher A. "Characterization of Simple Carbohydrate Structure by Glass Capillary Pyrolysis Gas Chromatography and Cluster Analysis" Analytical Chemistry, vol. 54, No. 4, Apr. 1982, pp. 741-747.
Sahota, Rachhpal S. and Morgan, Stephen L. "Vector Representation, Feature Selection, and Fingerprinting: An Application of Pattern Recognition to Pyrolysis-Gas Chromatography/Mass Spectrometry of Nucleosides" Analytical Chemistry, vol. 65, No. 1, Jan. 1, 1993, pp. 70-77.
Whiton, Robert S. and Morgan, Stephen L. "Modified Interface for Pyrolysis Gas Chromotography with Capillary Columns" Analytical Chemistry, vol. 57, No. 3, Mar. 1985, pp. 778-780.

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