Functionally substituted terpolymers and tetrapolymers of alpha-

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526281, 526282, C08F 420, C08F 3204

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active

040176690

ABSTRACT:
Addition terpolymers of ethylene with an .alpha.-olefin and an unsaturated, functionally substituted monomer. Addition tetrapolymers of ethylene with an .alpha.-olefin having 3-18 carbon atoms, a nonconjugated diene having only one polymerizable double bond, and an unsaturated, functionally substituted monomer. A process for preparing copolymers of ethylene with an unsaturated functionally substituted monomer, and optionally also with at least one of the following: an .alpha.-olefin having 3-18 carbon atoms and a nonconjugated diene having only one polymerizable double bond; wherein the monomers are contacted in the presence of a vanadium compound soluble in hydrocarbons and chlorinated hydrocarbons, in which vanadium is in the oxidation state of at least +3, an organoaluminum compound, and an organic compound having at least one carbon atom substituted by three halogen atoms which can be chlorine or bromine.

REFERENCES:
patent: 3723399 (1973-03-01), Amiard et al.
patent: 3748316 (1973-07-01), Collette et al.
patent: 3796687 (1974-03-01), Collette et al.

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