Functionalization of nanodiamond powder through fluorination...

Chemistry of inorganic compounds – Carbon or compound thereof – Elemental carbon

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

Reexamination Certificate

active

07820130

ABSTRACT:
The present invention is directed to functionalized nanoscale diamond powders, methods for making such powders, applications for using such powders, and articles of manufacture comprising such powders. Methods for making such functionalized nanodiamond powders generally comprise a fluorination of nanodiamond powder. In some embodiments, such methods comprise reacting fluorinated nanodiamond powder with a subsequent derivatization agent, such as a strong nucleophile.

REFERENCES:
patent: 2001/0031900 (2001-10-01), Margrave et al.
Ando, et al., Diffuse Reflectance Fourier-transform Infrared Study of the Plasma-fluorination of Diamond Surfaces using a Microwave Discharge in CF4, J. Chem. Soc. Faraday Trans. 1993; 89(16): 3105-3109.
Ando, et al., Direct interaction of elemental fluorine with diamond surfaces, Diamond and Related Materials 1996; 5: 1021-1025.
Kealey, et al., Fluorination of polycrystalline diamond films and powders. An investigation using FTIR spectroscopy, SEM, energy-filtered TEM, XPS and fluorine-18 radiotracer methods, J. Mater. Chem. 2001; 11: 879-886.
Liu, et al., Functionalization of Nanoscale Diamond Powder: Fluoro-, Alkyl-, Amino-, and Amino Acid-Nanodiamond Derivatives, Chem. Mater. 2004; 16: 3924-3930.
Rice Quantum Institute's Summer Colloquium (Aug. 9, 2002).
Smentkowski, et al., Fluorination of diamond surfaces by irradiation of perfluorinated alkyl iodides, Science 1996; 271(5246): 193.
Ando, et al., Direct interaction of elemental fluorine with diamond surfaces, Diamond and Related Materials 1996; 5: 1021-1025.
Shenderova, et al., Carbon Nanostructures, Critical Reviews in Solid State and Materials Science 2002; 27: 227-356.
Bondar', et al., Use of Nanodiamond Particles for Rapid Isolation of Recombinant Apooberlin fromEscherichia coli, Doklady Biochemistry 2000; 373: 129-131.
Wilks, et al., Properties and Applications of Diamond, Butterworth, Oxford, England (1997).
Pierson, Handbook of Carbon, Graphite, Diamond and Fullerenes, Noyes Publ. Park Ridge, New Jersey, USA (1993).
Shenderova et al., “Carbon nanostructures”, 27 Critical Reviews in Solid State and Materials Sciences (2002) p. 227.
Dolmatov, “Detonation synthesis ultradispersed diamonds: properties and applications”, 70 Russian Chemical Reviews (2001), p. 607.
Greiner et al., “Diamonds in detonation soot”, 333 Nature (1988), p. 440.
Kuznetsov et al., “Effect of explosion conditions on the structure of detonation soots . . . ”, 32 Carbon (1994), p. 873.
Alimova et al., “Electrophoresis of nanodiamond powder for cold cathode fabrication”, 17(2) J. Vac. Sci. Technol. B (1999), pp. 715-718.
Show et al., “Characterization an electrochemical responsiveness of boron-doped nanocrystalline . . . ”, 15 Chem. Mater. (2003), p. 879-888.
Choi et al., “Field emission from silicon and molybdenum tips coated with diamond powder by dielectrophoresis”, 69 Appl. Phys. Lett. (1996), p. 720-722.
Ralchenko et al., “Diamond-carbon nanocomposites: application for diamond film deposition . . . ” 8 Diamond Relat. Mater. (1999), p. 1496-1501.
Jiang et al., “Structural characteristics and field electron emission properties of nano-diamond/carbon films”, 236 J. Cryst. Growth (2002), p. 577-582.
Wang et al., “CVD polycrystalline diamond high-Q micromechanical resonators”, Proc. of The Fifteenth IEEE Internat. Conf. On Micro Electromechanical Systems (2002), p. 657-660.
Sekaric et al., “Nanomechanical resonant structures in nanocrystalline diamond”, 81 Appl. Phys. Lett. (2002), pp. 4455-4457.
Philip et al., “Elastic, mechanical, and thermal properties of nanocrystalline diamond films”, 93 J. Appl. Phys. (2003), p. 2164-2171.
Yang et al., “DNA-modified nanocrystalline diamond thin-films as stable, biologically active substrates”, 1 Nature Mater. (2002), p. 253-257.
Jiang et al., “FTIR studies on the spectral changes of the surface functional groups . . . ”, 92 J. Chem. Soc., Faraday Trans. (1996), p. 3401-5.
Hamers et al., “Cycloaddition chemistry of organic molecules with semiconductor surfaces”, 33 Acc. Chem. Res. (2000), p. 617-624.
Bent et al., “Organic functionalization of group IV semiconductor surfaces: principles, examples, applications and prospects”, 500 Surf. Sci. (2002), p. 879-903.
Hukka et al., “Chemisorption of hydrogen on the diamond . . . ”, 98 J. Phys. Chem. (1994), p. 12420-12430.
Hovis et al., “Cycloaddition chemistry at surfaces: reaction of alkenes with the diamond(001)-2x1 surface”, 122 J. Am. Chem. Soc. (2000), p. 732-733.
Wang et al., “Functionalization of diamond(001) by Diels-Alder chemistry”, 122 J. Am. Chem. Soc. (2000), p. 744-745.
Fitzgerald et al., “Functionalization of diamond(001) by cycloaddition of butadiene: first principles theory”, 122 J. Am. Chem. Soc. (2000), p. 12334-12339.
Hossain et al., “Diels-Adler reaction on the clean diamond(100)2x1 surface”, 38 Jpn. J. Appl. Phys. (1999), p. L1496-1498.
Miller et al., “Photochemical modification of diamond surfaces”, 12 Langmuir (1996), p. 5809-5817.
Smentkowski et al., “Fluorination of diamond surfaces by irradiation of perfluorinated alkyl iodides”, 271 Science (1996), p. 193.
Kim et al., “Photochemical attachment of fluorobutyl moieties on a diamond (110)-oriented surface . . . ”, 102 J. Phys. Chem. B (1998), p. 9290-9296.
Nakamura et al., “Chemical modification of diamond powder using photolysis of perfluoroazooctane”, Chem. Commun. (2003), p. 900-901.
Ando et al., “Direct interaction of elemental fluorine with diamond Surfaces”, 5 Diamond Relat. Mater. (1996), p. 1021-1025.
Kealey et al., “Fluorination of polycrystalline diamond films and powerders . . . ”, 11 J. Mater. Chem. (2001), p. 879-886.
Ando et al., “Diffuse reflectance Fourier-transform infrared study of the plasma fluorination of diamond surfaces . . . ”, 89 J. Chem. Soc., Faraday Trans. (1993), p. 3105-3109.
Touhara et al., “Property control of carbon materials by fluorination”, 38 Carbon (2000), p. 241-267.
Ferro et al., “Physicochemical properties of fluorinated diamond electrodes”, 107 J. Phys. Chem. B (2003), p. 7567-7573.
Ferro et al., “The 5-V window of polarizability of fluorinated diamond electrodes in aqueous solutions”, 75 Anal. Chem. (2003), p. 7040-7042.
Roeges, N., “Guide to the Complete Interpretation of Infrared Spectra of Organic Structures”, Wiley Publ., Chichester, England (1994).
Kawasaki et al., “Crystal structures of the fluorinated fullerenes C60F36 and C60F48” 103 J. Phys. Chem. B (1999), p. 1223.
Khabashesku et al., “Fluorination of single-wall carbon nanotubes and subsequent derivatization reactions”, 35 Acc. Chem. Res. (2002), p. 1087-1095.
Khabashesku, V. N. Chemistry of Carbon Nanotubes in Encyclopedia of Nanoscience and Nanotechnology, Ed. S. Nalwa, American Scientific Publishers, Los Angeles, (2004), vol. 1, p. 849.
The Aldrich Library of Infrared Spectra, Second Edition. Ed. C. J. Pouchert, Milwaukee, Wisconsin (1975).
Stenhagen, et al., “Atlas of Mass Spectral Data”, 1 Interscience Publ., (1969).
B.D. Cullity, “Elements of X-Ray Diffraction”, Second Edition (Boston: Addison-Wesley, 1978), p. 102.
Rice Quantum Institute's Summer Colloquium, Aug. 9, 2002.
Liu, “Functionalization of Nanoscale Diamond Powder: Fluoro-, Alkyl-, Amino Acid-Nanodiamond Derivatives”, Chem. Mater. 2004;16:3924-3930.
Liu, Y., N. Agrawal, Z. Gu, H. Peng, V.N. Khabashesku, and J.L. Margrave. “Fluorination of Nanodiamond.” PowerPoint Presentation Slides. Aug. 9, 2002.
Khabashesku, V.N. “Functionalization of Carbon Nanomaterials for Bio-Medical Applications.” PowerPoint Presentation Slides. Sep. 24, 2003.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Functionalization of nanodiamond powder through fluorination... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Functionalization of nanodiamond powder through fluorination..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Functionalization of nanodiamond powder through fluorination... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4231759

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.