Fuel and related compositions – Solid carbonaceous fuel dispersed in a liquid medium – The liquid medium is – or contains – hydrocarbon
Reexamination Certificate
1998-07-29
2001-09-25
Medley, Margaret (Department: 1714)
Fuel and related compositions
Solid carbonaceous fuel dispersed in a liquid medium
The liquid medium is, or contains, hydrocarbon
Reexamination Certificate
active
06293975
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to a fuel composition. More particularly, the present invention relates to a fuel composition derived from a waste stream, particularly a petroleum refinery waste stream.
BACKGROUND OF THE INVENTION
Waste product streams containing primarily water, and smaller amounts of nonaqueous liquids and solids, both organic and inorganic, are by-products of the refining, petrochemical and chemical industries, to name a few. For example, a typical waste stream from a refinery operation will contain about 80 percent-by-weight water, about 15 percent-by-weight oil, e.g., hydrocarbons and other nonaqueous liquids, and about 5 percent-by-weight solids. Due to environmental regulations, these waste stream pose disposal problems.
It is known to treat a refinery waste stream, commonly referred to as sludge which is a mixture of solids, water and oil products, in such a manner to obtain either a solids stream which is a slurry of solids, both inorganic and organic, in a primarily aqueous medium, the slurry generally containing from about 15 to about 20 percent-by-weight solids content, or a non-pumpable dry solids cake. Such slurries, containing a relatively small amount, i.e., less than about 10 percent-by-weight, of nonaqueous liquids, e.g., hydrocarbons, can be incinerated as for example, in furnaces used in regenerative spent sulfuric acid plants, cement kilns or the like. These prior art aqueous slurries have several disadvantages. For one, because of the high water content, they have a low heat value. Additionally, the solids content of the slurries cannot exceed about 20-25 percent lest they become so viscous as to be unpumpable at ambient temperature conditions. Accordingly, the cost of disposing of the slurries is increased because the transportation costs per unit weight of solids is relatively high. In the case of non-pumpable, dry solids cake, the solids content is generally 25 to 90 percent-by-weight. This cake requires special handling for disposal and is considerably more expensive than the slurries to dispose of.
SUMMARY OF THE INVENTION
It is therefore an object of the present invention to provide a new fuel composition which is pumpable.
Another object of the present invention is to provide a pumpable fuel composition derived from a waste stream containing water, nonaqueous liquids, inorganic solids and organic solids.
Still a further object of the present invention is to provide a pumpable fuel composition of a relatively high solids content which can be disposed of more economically.
The above and other objects of the present invention will become apparent from the description given herein and the claims.
The present invention provides a fuel composition comprising less than about 10 percent-by-weight water, greater than about 35 percent-by-weight solids, generally up to about 70 percent-by-weight solids, and from about 30 to about 70 percent-by-weight of a nonaqueous liquid. The fuel composition has a minimum heat value of about 7000 BTU per pound and a viscosity such that the composition is pumpable at ambient temperature.
DESCRIPTION OF THE PREFERRED EMBODIMENT
The fuel composition of the present invention comprises water, solids and nonaqueous, generally water-insoluble liquids. Generally speaking, the water will be present in an amount of less than about 10 percent-by-weight, more preferably in the range of from about 3 to about 8 percent-by-weight. The solids, which can include both inorganic and organic containing materials, will comprise greater than about 35 percent-by-weight, generally up to about 70 percent-by-weight, the solids generally comprising from about 12 to about 30 percent-by-weight inorganic solids and from about 12 to about 30 percent-by-weight organic solids. The organic solids are carbon-containing are substantially methylene chloride insoluble but because of their carbon content are usually combustible. In certain cases the solids content can be substantially all organic, i.e., carbon-containing, or all inorganic. The nonaqueous liquids will generally comprise from about 30 to about 70 percent-by-weight of the fuel composition. The nonaqueous liquid can be virtually any combustible organic material which is insoluble or has limited solubility in water. Non-limiting examples of suitable nonaqueous liquids include hydrocarbons, alcohols, ketones, ethers, aldehydes, etc., as well as mixtures of such compounds. Typically, the nonaqueous liquid is referred to as “oil.”. As used herein, oil refers to any mixture of organic compounds typically found in waste streams or sludges in refineries petrochemical plants and the like which are generally immiscible with water. While such oils primarily comprise hydrocarbons, other organic compounds can also be present.
The fuel compositions of the present invention can also include dispersant and/or surfactants such as lignosulfonates.
The fuel composition will have a minimum heat capacity of at least about 7000 BTU per pound, preferably greater than about 10,000 BTU per pound.
The fuel composition of the present invention, because it has a relatively high content of liquids which are less polar than water, does not become viscous rendering it unpumpable at ambient temperature. Prior art slurries used for fuel in furnaces or cement kilns suffer from the disadvantage that, because the water content is high, the solids content must be kept below about 25 percent-by-weight in order that the slurry can be handled by conventional pumps. As can be seen, the fuel composition of the present invention contains a minimum of about 35 percent-by-weight solids and can contain about up to 70 percent-by-weight solids and still be pumpable. This high solids loading is further advantageous in that transportation and disposal costs per unit weight of solids is reduced.
In the disposal of a typical waste stream, e.g., a refinery waste stream, EPA regulations and Boiler and Industrial Rules (BIF) permit the waste stream (sludge) to be incinerated, as for example in cement kilns, furnaces in spent sulfuric acid regeneration plants and the like, provided that the combustible solids plus any nonaqueous liquids present in the original waste stream have a minimum heat value of at least about 5000 BTU per pound. Thus, if the solids stream recovered from a typical refinery waste stream, which generally, primarily contains water, has a minimum heat value of at least 5000 BTU per pound, such a solids stream can be incinerated in the manner mentioned above. Alternately, if oil or other nonaqueous liquids recovered from the waste stream are added back to the solids stream recovered from the waste stream, and the mixture of the recovered solids stream and added back nonaqueous stream has a minimum heat capacity of at least 5000 BTU per pound, the mixture can also be incinerated as described.
As noted above, the composition of the present invention can be derived from refinery waste streams. Such streams can include, for example, AP1 separator sludge, dissolved air floatation float, slop oil emulsion solids, tank bottoms (leaded) heat exchanger bundle cleaning sludge, oily waste sludges from the refinery's primary side of the waste water treatment system and oily tank bottom sludges. However, the source or feed stream for the composition need not be a waste stream from a refinery. For example, in numerous petrochemical and chemical operations, waste streams, primarily aqueous in nature, are produced which pose the same or similar disposal problems in that they contain hazardous solids and nonaqueous liquids. Thus, the composition of the present invention can be derived from an), waste stream, regardless of source, which contains a liquid, nonaqueous fraction, a solids fraction and an aqueous fraction.
A typical waste stream which can be used as the source of the composition of the present invention will generally contain from about 5 to about 30 percent-by-weight water-insoluble, nonaqueous liquids, from about 50 to about 95 percent-by-weight water and from about 1 to about 10 percent-by-w,ei
Ruth Raymond R.
Scalliet Robert M.
Conley & Rose & Tayon P.C.
Medley Margaret
US Filter Corporation
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