Fuel cell nanocatalyst

Chemistry: electrical current producing apparatus – product – and – Having earth feature

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C502S101000

Reexamination Certificate

active

07622217

ABSTRACT:
A fuel cell cathode catalyst is provided comprising nanostructured elements comprising microstructured support whiskers bearing nanoscopic catalyst particles; wherein the catalyst comprises platinum and manganese and at least one other metal selected from the group consisting of Group VIb metals, Group VIIb metals and Group VIIIb metals other than platinum and manganese; wherein the volume ratio of platinum to the sum of all other metals in the catalyst is between about 1 and about 4 and wherein the Mn content is equal to or greater than about 5 micrograms/cm2 areal density. Typically, the volume ratio of manganese to the at least one other metal is between 10:90 and 90:10. Typically, the at least one other metal is Ni or Co. In addition, a fuel cell MBA comprising the present cathode catalyst is provided. In addition, methods of making the present cathode catalyst are provided.

REFERENCES:
patent: 3369938 (1968-02-01), Kroeger et al.
patent: 3382105 (1968-05-01), McBryar et al.
patent: 4021369 (1977-05-01), Lyons
patent: 4284835 (1981-08-01), Kim et al.
patent: 4340276 (1982-07-01), Maffitt et al.
patent: 4416801 (1983-11-01), Waller
patent: 4433082 (1984-02-01), Grot
patent: 4568598 (1986-02-01), Bilkadi et al.
patent: 4741744 (1988-05-01), Wu et al.
patent: 4812352 (1989-03-01), Debe
patent: 4824835 (1989-04-01), Mertens et al.
patent: 4866099 (1989-09-01), Hendy
patent: 5039561 (1991-08-01), Debe
patent: 5176786 (1993-01-01), Debe
patent: 5186877 (1993-02-01), Watanabe
patent: 5221455 (1993-06-01), Hanada et al.
patent: 5225391 (1993-07-01), Stonehart et al.
patent: 5294232 (1994-03-01), Sakairi et al.
patent: 5336558 (1994-08-01), Debe
patent: 5338430 (1994-08-01), Parsonage et al.
patent: 5472799 (1995-12-01), Watanabe
patent: 5523181 (1996-06-01), Stonehart et al.
patent: 5766787 (1998-06-01), Watanabe et al.
patent: 5766788 (1998-06-01), Inoue et al.
patent: 5840192 (1998-11-01), El Moussaoui et al.
patent: 5879827 (1999-03-01), Debe et al.
patent: 5879828 (1999-03-01), Debe et al.
patent: 6040077 (2000-03-01), Debe et al.
patent: 6059943 (2000-05-01), Murphy et al.
patent: 6242135 (2001-06-01), Mushiake
patent: 6319293 (2001-11-01), Debe et al.
patent: 6335112 (2002-01-01), Asukabe et al.
patent: 6624328 (2003-09-01), Guerra
patent: 6630263 (2003-10-01), McElroy
patent: 6635384 (2003-10-01), Bahar et al.
patent: 6649295 (2003-11-01), Hamrock et al.
patent: 6680138 (2004-01-01), Honma et al.
patent: 6864006 (2005-03-01), Honma et al.
patent: 2002/0004453 (2002-01-01), Haugen et al.
patent: 2002/0015875 (2002-02-01), Kim
patent: 2002/0058172 (2002-05-01), Datz et al.
patent: 2002/0076594 (2002-06-01), Fukuda et al.
patent: 2002/0093008 (2002-07-01), Kerres et al.
patent: 2002/0132157 (2002-09-01), Finkelshtain et al.
patent: 2003/0008196 (2003-01-01), Wessel et al.
patent: 2003/0013004 (2003-01-01), Oyanagi et al.
patent: 2004/0043283 (2004-03-01), Cipollini et al.
patent: 2004/0048129 (2004-03-01), Taft, III et al.
patent: 2004/0048466 (2004-03-01), Gore et al.
patent: 2004/0116742 (2004-06-01), Guerra
patent: 2004/0121210 (2004-06-01), Hamrock et al.
patent: 2004/0251450 (2004-12-01), Kerres et al.
patent: 2005/0069755 (2005-03-01), Vernstrom et al.
patent: 2005/0136308 (2005-06-01), Andrews et al.
patent: 2006/0046120 (2006-03-01), Merzougui et al.
patent: 2006/0063055 (2006-03-01), Frey et al.
patent: 0 459 820 (1997-07-01), None
patent: 0 631 337 (2000-07-01), None
patent: 1 133 806 (2002-09-01), None
patent: 1 449 233 (1976-09-01), None
patent: 1 534 359 (1978-12-01), None
patent: 54-82042 (1979-06-01), None
patent: 2001/118591 (2001-04-01), None
patent: 2001-321664 (2001-11-01), None
patent: 2003-059497 (2003-02-01), None
patent: 2003-123777 (2003-04-01), None
patent: HEI-2003-282097 (2003-10-01), None
patent: 2004-273384 (2004-09-01), None
patent: 2000-0063843 (2000-06-01), None
patent: WO 00/24074 (2000-04-01), None
patent: WO 01/54216 (2001-07-01), None
patent: WO 02/061871 (2002-08-01), None
M. Debe, A. Steinbach, K. Lewinski, G. Haugen, G. Vernstrom, R. Atanasoski, A. Hester, P. Turner, R. Ziegler, J. Larson, M. Hicks, and P. Serim; “Activities Of Low Pt Loading, Carbon-Less, Ultra-Thin Nanostructured Film-Based Electrodes For PEM Fuel Cells And Roll-Good Fabricated MEA Performances in Single Cells And Stacks”, 2003 Fuel Cell Seminar, Fuel Cells for Secure, Sustainable Energy, Abstracts, Nov. 3-7, 2003, Miami Beach, Florida, Fontainebleau Hilton Hotel, pp. 812-815.
M. Ludvigsson, J. Lindgren, and J. Tegenfeldt; “Incorporation And Characterisation Of Oxides Of Manganese, Cobalt, and Lithium Into 117 Membranes”, Journal of Materials Chemistry, vol. 11, No. 4, Apr. 2001, pp. 1269-1276.
A. Michas, J. M Kelly, R. Durand, M. Pineri, and J.M.D. Coey; Preparation, Characterization And Catalytic Properties Of Perfluorosulfonated Ion-Exchange Membranes Containing Surface-Concentrated, Hydrated Ruthenium Oxide Particles, Journal of Membrane Science, vol. 29, No. 3, Dec. 15, 1986, pp. 239-257.
G. M. Chow et al.; “Fabrication Of Biologically Based Microstructure Composites For Vacuum Field Emission”, Materials Science and Engineering, A158, 1992, pp. 1-6.
K. K. Kam, M. K. Debe, R. J. Poirier, and A. R. Drube; “Summary Abstract: Dramatic Variation Of The Physical Microstructure Of A Vapor Deposited Organic Thin Film”, J. Vac. Sci. Technol, A, 5(4), Jul./Aug. 1987, pp. 1914-1916.
M. K. Debe, K. K. Kam, J. C. Liu, and R. J. Poirier; “Vacuum Vapor Deposited Thin Films Of A Perylene Dicarboximide Derivative: Microstructure Versus Deposition Parameters”, J. Vac. Sci. Technol. A, 6 (3), May/Jun. 1988, pp. 1907-1911.
M. K. Debe and R. J. Poirier; “Effect Of Gravity On Copper Phthalocyanine Thin Films III: Microstructure Comparisons Of Copper Phthalocyanine Thin Films Grown in Microgravity And Unit Gravity”, Thin Solid Films, vol. 186, 1990, pp. 327-347.
Y. Sadaoka, T. A. Jones, G. S. Revell, W. Gopel; Effects Of Morphology on NO2Detection In Air At Room Temperature With Phthalocyanine Thin Films, Journal of Materials Science, vol. 25, 1990, pp. 5257-5268.
S. Ohnuma, Y. Nakanouchi, and T. Masumoto; “Amorphous Ultrafine Metallic Particles Prepared By Sputtering Method”, Rapidly Quenched Metals, Proc. Of the Fifth Int. Conf. On Rapidly Quenched Metals, Wurzburg, Germany, Sep. 3-7, 1984, S. Steeb et al., eds., Elsevier Science Publisher B.V., New York, 1985, pp. 1117-1124.
P. K. Lee and M. K. Debe, “Measurement And Modeling Of The Reflectance-Reducing Properties Of Gradient Index Microstructured Surfaces”, Photographic Science and Engineering, vol. 24, (4), Jul./Aug. 1980, pp. 211-216.
H. Tang, J. H. Chen, Z. P. Huang, D. Z. Wang, Z. F. Ren, L. H. Nie, Y. F. Kuang, and S. Z. Yao; “High Dispersion And Electrocatalytic Properties Of Platinum On Well-Aligned Carbon Nanotube Arrays”, Carbon, vol. 42, 2004, pp. 191-197.
A. Bonakdarpour et al., “Corrosion of Transition Metals, in Pt1−xMxProton Exchange Membrane Fuel Cell (PEMFC) Electrocatalysts”, 2004 Fall Meeting of the Electrochemical Society of Japan, Hawaii, Oct. 3-8, 2004.
Fuqiang Liu, Baolian Yi, Danmin Xing, Jingrong Yu, Zhongjun Hou, Yongzhu Fu; “Development of Novel Self-Humidifying Composite Membranes for Fuel Cells”,Journal of Power Sources, vol. 124, 2003, pp. 81-89.
J. Guan and G. Li, “Studies on Preparation of Ultrafine MnO Particles and Its Eletrocatalytic Performance in PEMFC”, Huaxue Shijie 43 [1] (2002) pp. 7-9.
S. Kawatsu and M. Iwase, “Electrocatalysts for Polymer Electrolyte Fuel Cells”, Jidosha Gijutsukai Ronbunshu (Transaction of the Society Automotive Engineers of Japan), vol. 28, No. 4, (Oct. 1997), pp. 39-42.
U.S. Appl. No. 10/945,178, filed Sep. 20, 2004, “Fuel Cell Durability”, now pending.
U.S. Appl. No. 10/944,998, filed Sep. 20, 2004, “Durable Fuel Cell”, now pending.
U.S. Appl. No. 11/248,441, filed Oct. 12, 2005, “Ternary Nanocatalyst and Method of Making”, now pending.
U.S. Ap

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Fuel cell nanocatalyst does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Fuel cell nanocatalyst, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Fuel cell nanocatalyst will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4132544

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.