Free radical polymerization of olefinically unsaturated monomers

Details Free radical polymerization of olefinically unsaturated monomers Free radical polymerization of olefinically unsaturated monomers

1975-01-27

1976-06-29

Tillman, Murray

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260470A, 260 63UY, 260 75A, 260 75T, C08L 6702, C08L 6706, C07C 6902, C07C17918

Patent

active

039668401

ABSTRACT:
The esters of pinane hydroperoxide with carboxylic acids are effective free radical initiators for the polymerizaton of olefinically unsaturated monomers, and are superior to the corresponding esters of tert-butyl peroxide by their shorter half-life at equal temperature.

REFERENCES:
patent: 2264354 (1941-12-01), Alder et al.
patent: 2892814 (1959-06-01), Koch et al.
patent: 2957030 (1960-10-01), Bankert
patent: 3061554 (1962-10-01), Vartanian et al.
patent: 3231599 (1966-01-01), Kilsheimer et al.
patent: 3706818 (1972-12-01), Mageli et al.
patent: 3850891 (1974-11-01), Crawford

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