Fourier transform NMR spectroscopy employing a phase modulated r

Electricity: measuring and testing – Measuring – testing – or sensing electricity – per se – Frequency of cyclic current or voltage

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324 5A, G01R 3308

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active

039684245

ABSTRACT:
A nuclear magnetic resonance Fourier transform spectrometer includes a pulse modulated rf transmitter for delivering a train of radio frequency pulses having a pulse width pulse repetition rate to generate Fourier side bands to cover the spectral lines of the sample to be analyzed for exciting resonance of different resonance lines, if any, within the sample. Resonance of the sample is scanned in between successive transmitted pulses to obtain a multiplicity of successive time displaced components which are sampled and stored in a multiplicity of memory channels of a computer for time averaging thereof. The time averaged signal components are periodically read out and Fourier transformed to obtain a time averaged spectrum of the sample under analysis. Anomalous phase and intensity effects in the detected spectral lines are avoided by periodically shifting the phase of the pulse modulated carrier signal from one phase to another of at least three different relative phases in accordance with a predetermined sequence.

REFERENCES:
patent: 3824452 (1974-07-01), Freeman

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