Compositions: coating or plastic – Coating or plastic compositions – Molds and mold coating compositions
Reexamination Certificate
1999-10-07
2002-04-16
Marcantoni, Paul (Department: 1755)
Compositions: coating or plastic
Coating or plastic compositions
Molds and mold coating compositions
C501S106000, C501S133000, C501S153000, C501S154000, C164S527000, C164S528000, C164S529000, C164S359000, C523S218000, C523S219000
Reexamination Certificate
active
06372032
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to a foundry exothermic assembly, particularly to a foundry exothermic assembly formed by mixing an oxidizable metal, an oxidizing agent, an optional pro-oxidant, a foundry refractory aggregate and hollow glass microspheres, and shaping and curing the mixture. The assembly is characterized in that its matrix is composed of the oxidizable metal, the oxidizing agent, the optional pro-oxidant and the foundry refractory aggregate, and the hollow glass microspheres are dispersed and embedded in the matrix.
By “foundry exothermic assembly” is meant an exothermic riser sleeve, an exothermic core, an exothermic neck-down core, an exothermic mold, an exothermic pad, or a similar article.
Particularly typical of the foundry exothermic assembly according to the present invention is an exothermic riser sleeve for use in a mold. When the riser sleeve is attached to a mold and a molten metal is poured into the mold, the riser sleeve undergoes exothermic reaction. The heat produced by this reaction, together with the heat of the molten metal, melts and disperses the hollow glass microspheres dispersed and embedded in the riser sleeve matrix, whereby small pores form in the matrix to make it porous. As the heat-retaining effect of the riser sleeve relative to the molten metal is therefore markedly enhanced, the riser sleeve manifests excellent feeding effect.
2. Description of the Prior Art
Typical of conventional foundry exothermic assemblies is the exothermic riser sleeve obtained by shaping and curing, as main materials, a foundry refractory aggregate such as zircon sand, an exothermic material such as aluminum, and an oxidizing agent such as potassium nitrate. Since the apparent specific gravity of such a foundry exothermic assembly is around 1.2-1.5 g/cc, it cannot provide a very high level of heat retentivity with respect to the cast metal between the time of pouring the molten metal into the mold and the time the metal solidifies from the molten state.
SUMMARY OF THE INVENTION
An object of this invention is to provide a foundry exothermic assembly, more specifically a foundry exothermic assembly intended for attachment to a mold so that when molten metal is poured into the mold, the matrix of the assembly undergoes exothermic reaction and the heat produced by this reaction, together with the heat of the molten metal, melts and disperses the hollow glass microspheres embedded in the assembly matrix, thus causing small pores to form at the locations where the hollow glass microspheres were embedded and make the matrix porous, whereby the foundry exothermic assembly can manifest a very high level of heat retentivity with respect to the cast metal over the period from the molten state to the solidified state of the metal, good refractory property, and outstanding feeding effect.
To achieve this object, the present invention provides a foundry exothermic assembly which is formed by mixing hollow glass microspheres and an inorganic or organic binder with matrix forming constituents including an oxidizable metal, an oxidizing agent, a foundry refractory aggregate and, optionally, a pro-oxidant, and shaping and curing the mixture, the hollow glass microspheres being dispersed and embedded in the assembly matrix.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
The foundry exothermic assembly according to the present invention is characterized in that it has hollow glass microspheres dispersed and embedded in its matrix.
The present invention does not particularly specify the type of material used to produce the hollow glass microspheres. They can, for example, be produced from an ordinary glass material like the soda-lime-silicate glass (SiO
2
: about 72%, Na
2
O: about 14-16%, CaO: about 5-9%) commonly used as a material for plate glass and glass for bottles, tableware and other containers. Any glass material suffices so long as its melting point is around 800° C. at the highest.
The amount of the hollow glass microspheres contained in the matrix is at least 10 wt %, preferably 20-40 wt %. The diameter of the hollow glass microspheres, while not particularly limited, should generally be 3.0 mm or less, preferably 1.2 mm or less.
The foundry exothermic assembly according to the present invention has hollow glass microspheres dispersed and embedded throughout its matrix. Take, for example, the exothermic riser sleeve that is typical of the foundry exothermic assembly according to the invention. When the exothermic riser sleeve is attached at the riser of a mold and molten metal is poured into the mold, the hollow glass microspheres dispersed and embedded in the matrix of the riser sleeve melt and disperse during the process of molten metal casting and solidification upon being heated to a temperature of, at the highest, around 800° C. by the heat of the molten metal and the heat generated by a combustion reaction that the heat of the molten metal triggers in the exothermic material (oxidizable metal and oxidizing agent) constituting the matrix of the riser sleeve. As a result, small pores form at the locations where the hollow glass microspheres were dispersed and embedded in the sleeve matrix. Since the matrix therefore becomes porous, the heat-retaining property of the matrix is markedly enhanced while its refractoriness remains unchanged. The riser sleeve can therefore produce an excellent feeding effect.
The mixture of materials for producing the foundry exothermic assembly according to the present invention is obtained by mixing hollow glass microspheres with an oxidizable metal, an oxidizing agent, a foundry refractory aggregate and, optionally, a pro-oxidant, and then adding an inorganic or organic binder and, optionally, a curing catalyst. The resulting mixture is shaped and cured to obtain the foundry exothermic assembly by a known sand mold molding method such as the CO
2
process, the self-harding process, the fluid sand mixture process, the hot box process or the cold box process.
The components of the material mixture according to the present invention that produce the exothermic reaction under heating by the molten metal poured into the mold are the oxidizable metal and the oxidizing agent, plus, optionally, if required, the pro-oxidant.
The oxidizable metal is typically powdered or granular aluminum, but magnesium and similar metals can also be used. Usable oxidizing agents include iron oxide, manganese dioxide, nitrate and potassium permanganate.
The foundry exothermic assembly according to the present invention can, as required, optionally contain a pro-oxidant such as cryolite (Na
3
AlF
6
), potassium aluminum tetrafluoride or potassium aluminum hexafluoride.
Usable foundry refractory aggregates include, but are not limited to, aluminum ash (slag occurring during melting of aluminum ingot, which consists chiefly of alumina but also contains some amount of metallic aluminum and the flux used during melting), silica, zircon, magnesium silicate, olivine, quartz and chromite.
The binder added to enable shaping of the material mixture for producing the foundry exothermic assembly according to the present invention can be any of various known types. Specifically, any type of binder can be used insofar as it enables the material mixture to be cured in the presence of a curing catalyst to a degree that ensures reliable maintenance of the shape of the particular one of the various kinds of foundry exothermic assemblies to be fabricated. Usable binders include, for example, phenolic resin, phenol-urethane resin, furan resin, alkaline phenol-resol resin, and epoxy alkaline resin.
To be effective, these binders should be added in an amount of at least around 5 wt % based on the weight of the foundry exothermic assembly.
In a preferred embodiment of the present invention, hollow glass microspheres are added to a mixture composed of powdered and/or granular aluminum, aluminum ash, iron oxide and cryolite, whereafter phenol-urethane resin is used as binder to shape and cure a foundry exothermic assembly, typically,
Marcantoni Paul
Wenderoth , Lind & Ponack, L.L.P.
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