Fouling prevention in polymerization reactors

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S064000, C526S065000, C526S918000, C422S135000

Reexamination Certificate

active

07745552

ABSTRACT:
Reactor designs and processes for operating such reactor designs to minimize or eliminate fouling in homogeneous polymerization processes (solution and supercritical). The process includes providing a reactor with one or more feed entry ports, wherein the reactor feed components are fed through each of the one or more feed entry ports at a linear velocity of greater than or equal to 0.3 m/min. The one or more feed entry ports may also be optionally extended beyond the interior reactor wall by greater than or equal to 2% of the internal radius of the reactor to further decrease the propensity for fouling. A stirred reactor may also include a stirrer feed port for purging the stirrer with a stirrer purge stream at a linear velocity of greater than or equal to 0.3 m/min to decrease stirrer fouling.

REFERENCES:
patent: 3451785 (1969-06-01), Rohlfing et al.
patent: 3737288 (1973-06-01), Hochman
patent: 6969490 (2005-11-01), Marx et al.
patent: 7022780 (2006-04-01), Marx et al.
patent: 2006/0025545 (2006-02-01), Brant et al.
patent: 2006/0211832 (2006-09-01), Brant et al.
patent: 300291 (1917-09-01), None
patent: WO 93/11171 (1993-06-01), None
patent: WO 2006/044149 (2006-04-01), None
“Operation of the Reactor with a Sealed Electric Motor in Manufacture of Ditolyethane”.

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