Formation of TiO.sub.2 pigment by spray calcination

Plastic and nonmetallic article shaping or treating: processes – Formation of solid particulate material directly from molten... – By extrusion spraying or gravity fall through orifice

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106403, 106404, 106430, 106436, 106438, 106441, 106442, 106449, 423610, 423611, 423615, C01B 1320, C01B 1318, C09B 136

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058338926

ABSTRACT:
In a method of producing TiO.sub.2 pigment particles a TiO.sub.a X.sub.b (OH).sub.c -based precursor is suspended in a liquid with or without fuel additives. The suspension is then sprayed to form droplets. The droplets are transported into a flow reactor with a carrier gas. The droplets are decomposed in the flow reactor at high temperatures to form TiO.sub.2 pigment particles which are collected downstream of the flow reactor. In a preferred embodiment, a colloidal suspension of an insoluble TiO(SO.sub.4).sub.b (OH).sub.c precipitate with suitable fuel additives was spray-calcined at 900.degree. to 1200.degree. C. to produce pigment-quality TiO.sub.2. The primary particle size of the TiO.sub.2 pigment particles is between 150-250 nm and the particles are minimally aggregated.

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