Formation of superconducting Bi-Sr-Ca-Cu-O films by organometall

Superconductor technology: apparatus – material – process – Processes of producing or treating high temperature... – Using an organometallic intermediate

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505734, 505730, 505742, 427 62, 4272553, 4272552, 4272551, 4271263, C23C 1600, B05D 512

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053148665

ABSTRACT:
A CVD process for forming a layer or layers of superconducting materials on a semiconductor substrate in which volatile organometallic compounds of bismuth, strontium, calcium and copper are heated in the presence of a carrier gas in a first chamber free of hydrolyzing agents. Under conditions free of hydrolyzing agents, the carrier gas transports a predetermined quantity of the volatile organometallic compounds of the bismuth, strontium, calcium and copper to a deposition chamber. The compounds are decomposed and deposit mixed oxides on the substrate. Subsequent to deposition of the mixed oxides of the desired elements the layer is sintered in an oxygen-rich atmosphere, and formed into a superconducting film by subsequent slow cooling still in an oxygen-rich atmosphere.

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