Formation of 1-phenylvinyl-1-phosphonic acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus acids or salts thereof

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C07C 6200

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053918169

ABSTRACT:
A process for forming 1-phenylvinyl-1-phosphonic acid utilizes reacting a mixture of phosphorus trihalide, such as phosphorus trichloride, and acetophenone with water, under conditions in which the water is gradually added to the mixture with cooling to form a reaction mixture, which can be sparged of excess acetophenone with aqueous acid while under vacuum, comprising the 1-phenylvinyl-1-phosphonic acid. This product can be recovered from the reaction mixture by recrystallization from aqueous mineral acid, such as hydrochloric acid.

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Derwent Patent Abstract 39482R, Oct. 28, 1967.
Derwent Patent Abstract 86-002165/01, Oct. 28, 1985.
Journal of the American Chemical Society vol. 44, pp. 2530-2536 (1922).

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