Foam-fluid for fracturing subterranean formations

Details Foam-fluid for fracturing subterranean formations Foam-fluid for fracturing subterranean formations

1999-12-29

2002-06-25

Tucker, Philip (Department: 1712)

Earth boring, well treating, and oil field chemistry

Well treating

Contains intended gaseous phase at entry into wellbore

C507S922000, C507S240000, C507S259000

Reexamination Certificate

active

06410489

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to the field of fluids for fracturing subterranean formations, such as the formations surrounding oil or gas wells, to increase their permeability, and thereby increase the potential flow of recoverable hydrocarbons therefrom.
BACKGROUND OF THE INVENTION
In order to improve the recovery of hydrocarbons from oil and gas wells, the subterranean formations surrounding such wells can be fractured. That is, fluid can be introduced into the formations through the well bores, under high pressure, to open the pores and cracks in the formations. The fluids preferably are loaded with proppants, which are particles of hard material such as sand, to wedge open cracks or pores in the formation, and thereby permanently increase permeability and hydrocarbon flow. Therefore, the fracturing fluids are preferably of high viscosity, and therefore capable of carrying effective volumes of proppant material.
Preferably, the fracturing fluid is susceptible of viscosity drop, so as to be easily removed from the well after fracturing. The fluid should also be fairly non-toxic to the well. That is, it should not leave residue that will form a cake to clog the well, or that will leave undesisrable traces in the recoverable hydrocarbons that may be expensive to remove.
Fracturing fluids in common use include aqueous gels and hydrocarbon gels, found by the introduction of cross-linkable polymers into an aqueous or hydrocarbon fluid, followed by the catalyzed cross-linking of the polymers, and the subsequent breaking of the gels, for instance by pH adjustment. These types of systems are quite effective, but require extensive well clean up.
It has been proposed, for instance in U.S. Pat. No. 5,551,516, to provide a fracturing fluid with good viscosity and little residue by combining an inorganic salt stabilizer, a surfactant/thickener and an organic salt or alcohol. The fluid may also contain a gas, and thereby be in the form of a foam. The fluid disclosed in U.S. Pat. No. 5,551,516 develops viscosity of between 150 and 200 cp @ 170 sec
−1
at temperatures of about 40°-50° C., and surfactant loadings of up to about 5%.
Similar results for viscoelastic surfactant fluids utilizing a single surfactant have been reported by Brown et al in “Use of Viscoelastic Carrier Fluid in Frac-Pack Applications, SPE 31114 (1996) and Stewart et al, “Use of Solids-Free Viscous Carrying Fluid in Fracturing Applications: An Economic and Productivity Comparison in Shallow Completions” SPE 30114 (1994).
It is known, moreover, to utilize a surfactant in an aqueous medum as the external phase of a CO
2
foam, as shown in U.S. Pat. No. Re 32 302. The surfactant in such a foam may be an alkyl quaternary amine, a betain, a sulfated alkoxylate, or an ethoxylated linear alcohol. A foam using alpha olefin sulfonate as a surfactant, with a polymer such as a guar, is shown in U.S. Pat. No. 5,556,760.
The object of the present invention is to provide a fracturing foam utilizing an anionic surfactant in combination with a cationic surfactant, in water, as an external phase which at total loadings of up to about 6%, but usually less than 1%, surfactant delivers viscosity at 10°-70° C.
The applicant has found that a combination of an anionic surfactant, such as sodium xylene sulfonate, with a cationic surfactant such as N,N,N, trimethyl-1-octadecamonium chloride will form a viscoelastic gel very quickly, and can be mixed batch-wise in advance, or on-the-fly for use as a fracturing fluid. Inorganic salts may be added as stabilizers, but these are not strictly necessary.
At fairly low total surfactant loadings, foams are favorably formed, using, by volume, 50%-96%, or more of CO
2
.
For instance, a loading of 3 L/m
3
of each of a cationic surfactant such as N,N,N, trimethyl-1-octadecamonium chloride and an anionic surfactant such as sodium xylenesulfonate, with no additional foaming agent, yields a gel with 25 cp viscosity at room temperature, and favorable foaming characteristics.
In a broad aspect, then, the present invention relates to a fracturing foam for use in fracturing subterranean formations surrounding oil and gas wells comprising water, an anionic surfactant, and a cationic surfactant, and from 53% to 96% or more of CO
2
by volume.
In one embodiment, the cationic surfactant is added to the water in a quantity of from about 2 L/m
3
to about 60 L/m
3
.
In another embodiment, the anionic surfactant is added to the water in quantities of about 2.0 L/m
3
to about 30 L/m
3
.


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