Fluoroxy compound solutions

Details Fluoroxy compound solutions Fluoroxy compound solutions

1984-04-18

1986-02-04

Jiles, Henry R.

Compositions

Oxidative bleachant, oxidant containing, or generative

Free halogen or oxy-halogen acid type

260453RX, 560227, 568435, 568420, 568319, 568354, 568397, 568484, 568807, A62D 300, C01B 700, C07C 6962

Patent

active

045684782

ABSTRACT:
There is disclosed a solution of at least one fluoroxy compound, wherein said solution has a fluoroxy compound concentration of at least 0.5 meq/liter; said concentration containing about 35 to 100% of an acyl hypofluorite, based on the total number of equivalents of fluoroxy compounds present. The acyl hypofluorite has the formula X(CF.sub.2).sub.n COOF wherein X is H or F and n is 5 to 16. The solution is prepared by treating a suspension of a corresponding specified alkali salt with excess F.sub.2, and is useful as a selective fluorinating agent.

REFERENCES:
patent: 3415865 (1968-12-01), Prager et al.
patent: 3420866 (1969-01-01), Prager et al.
patent: 3684786 (1972-08-01), Chandrasekaran
Porter et al., J. Am. Chem. Soc., 79:5625-5627 (1957).
Cady et al., J. Am. Chem. Soc., 75:2501-2502 (1953).
Menefee et al., J. Am. Chem. Soc., 76:2020-2021 (1954).
Thompson et al., J. Am. Chem. Soc., 89:2263-2267 (1967).
Barton et al., Chem. Comm., 122-123 (1972).
Rozen et al., Tetrahedron Letters No. 8, 725-727 (1979).
Rozen et al., J. Am. Chem. Soc., 101:2782-2784 (1979).
Rozen et al., J. Fluorine Chem., 16:19-31 (1980).
Rozen et al., J. Org. Chem., 45:672-678 (1980).
Lerman et al., J. Org. Chem., 46:4629-4631 (1981); 48:724-727 (1983).

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