Fluorourethane additives for water-dispersed coating composition

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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4273855, 427393, 524507, 524591, 524839, 524840, 528 44, 528 63, 528 70, C08J 300, C08K 320, C08L 7500, B05D 302

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058279199

ABSTRACT:
Fluorourethane additives for water-dispersed coating compositions comprising the product of the reaction of 1) at least one diisocyanate, or polyisocyanate or a mixture of polyisocyanates containing at least three isocyanate groups per molecule, (2) at least one fluorochemical compound containing at least one Zerewitinoff hydrogen in an amount sufficient to react with 5% to 80% of the isocyanate groups in the diisocyanate or polyisocyanate, (3) at least one compound of the formula R.sub.10 --(R.sub.2).sub.k --YH in an amount sufficient to react with 5% to 80% of the isocyanate groups in the diisocyanate or polyisocyanate and wherein R.sub.10 is a C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 omega-alkenyl radical, or C.sub.1 -C.sub.18 omega-alkenoyl; R.sub.2 is --C.sub.n H.sub.2 same or different and are H or a C.sub.1 -C.sub.6 alkyl radical, n is 0 to 12, p is 1 to 50; Y is O, S, or N(R.sub.7) wherein R.sub.7 is H or C.sub.1 -C.sub.6 alkyl; and k is 0 or 1; and optionally (4) water in an amount sufficient to react with 5% to 60% of the isocyanate groups in the diisocyanate or polyisocyanate are disclosed.

REFERENCES:
patent: 5039739 (1991-08-01), Padget et al.
patent: 5350795 (1994-09-01), Smith et al.
patent: 5410073 (1995-04-01), Kirchner
patent: 5411766 (1995-05-01), Kirchner
patent: 5414111 (1995-05-01), Kirchner
Gauntt, D.L. et al., A Soil Resistant Treatment for Low Gloss Coatings, J. Coatings Technology, 63, No. 803, 25-32, Dec. 1991.

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