Fluorosulfonylperfluoroalkyl compounds

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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560145, 560150, 562605, 558437, C07C14370

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active

046134670

ABSTRACT:
A novel fluorinated copolymer is prepared by copolymerization of a fluorinated olefin with a novel sulfur containing fluorinated vinylether of the formula: ##STR1## wherein k is 0 or 1 and l is an integer of 3 to 5, which is prepared from starting materials which are also novel. Said copolymer is useful for preparation of a fluorinated cation exchange membrane having carboxylic acid groups and/or sulfonic acid groups which can be used advantageously in electrolysis of an aqueous alkali metal halide solution with improved electrolysis performance.

REFERENCES:
patent: 2852554 (1958-09-01), England
patent: 3301893 (1967-01-01), Putnam et al.
patent: 4332954 (1982-06-01), Koshar
Ragulin, L. I. et al., Chemical Abstracts, vol. 68 (1968) #48,977e.
Breslow, David S. et al. Multi-Sulfur and Sulfur and Oxygen Five-and Six Membered Heterocycles, Part 1. (1966) Interscience, Publ. pp. 78-80.
Sokol'skii, G. A. et al. Chemical Abstracts, vol. 68 (1968) #39,564r Chemical Abstracts Cumm. Index 1967-1971--Formula Index p. 361F.

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