Fluorosulfates of hexafluoroisobutylene and its higher...

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfonic acids or salts thereof

Reexamination Certificate

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C562S113000, C570S124000

Reexamination Certificate

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07579499

ABSTRACT:
Hexafluoroisobutylene and its higher homologs are easily reacted with SO3to give fluorosulfates of the formula CH2═C(R)CF2OSO2F, wherein R is a linear branched or cyclic fluoroalkyl group comprised of 1 to 10 carbon atoms and may contain ether oxygen. These compounds react under mild conditions with many nucleophiles to give CH2═C(R)CF2X, where X is derived from the nucleophile. This reaction provides a route to many substituted hexafluoroisobutylenes, which copolymerize easily with other fluoro- and hydrocarbon monomers such as vinylidene fluoride and ethylene.

REFERENCES:
patent: 2852554 (1958-09-01), England
patent: 3706723 (1972-12-01), Chandrasekaran et al.
patent: 4131740 (1978-12-01), England
patent: 4235804 (1980-11-01), Krespan
patent: 6140436 (2000-10-01), Doyle et al.
patent: 7276624 (2007-10-01), Cherstkov et al.
patent: 7301059 (2007-11-01), Cherstkov et al.
patent: 7531689 (2009-05-01), Cherstkov et al.
patent: 2003/0013816 (2003-01-01), Bekiarian et al.
patent: 0 121 073 (1987-07-01), None
patent: 0 728 776 (1998-10-01), None
patent: 1 148 041 (2001-10-01), None
patent: 1 219 063 (1971-01-01), None
patent: WO 00/55130 (2000-09-01), None
patent: WO 01/37043 (2001-05-01), None
patent: WO 02/093261 (2002-11-01), None
Viacheslav A. Petrov, J. Org. Chem., vol. 63, No. 9, pp. 2988-2992 (1998).
March, Jerry, Advanced Organic Chemistry, 4th Edition, Wiley, New York, 1992, p. 205.
Petrov, Journal of Organic Chemistry, 1998, 63, pp. 2988-2992.

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