Fluorosilicone rubber composition

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524588, 524866, 528 15, 528 24, C08L 8307, C08K 336

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active

049887580

ABSTRACT:
The fluorine-substituted organopolysiloxane as the principal ingredient of the inventive silicone rubber composition has vinyl groups to serve as the cross-linking points at the molecular chain terminals while at least the penultimate siloxane unit or the silicon atom adjacent to the terminal silicon atom has no fluorine-substituted hydrocarbon group bonded to the silicon atom. Being freed from the steric hindrance due to the bulky fluorine-substituted hydrocarbon group bonded to the adjacent silicon atom, the vinyl group bonded to the terminal silicon atom can pertain to the cross-linking reaction much easier than otherwise so that the silicone rubber composition of the invention containing an organic peroxide or a combination of an organohydrogenpolysiloxane and a platinum catalyst as a curing agent can be rapidly cured to give a cured silicone rubber article having excellent resistance against oils and organic solvents as well as mechanical properties.

REFERENCES:
patent: 3050492 (1962-08-01), Polmanteer et al.
patent: 3629297 (1971-12-01), Antonen
patent: 4525528 (1985-06-01), Bush et al.
patent: 4529792 (1985-07-01), Bluestein
patent: 4585848 (1986-04-01), Evans et al.
patent: 4654408 (1987-03-01), Okinoshima
patent: 4742101 (1988-05-01), Yoshida
Noll; Chemistry and Technology of Silicones; Academic Press; 1968; pp. 400, 401.

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