Fluorometric analysis of chloride ion and chemical sensor theref

Chemistry: analytical and immunological testing – Halogen containing – In aqueous solution

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436124, 436164, 436165, 436169, 436172, 436800, 422 56, 422 8205, 422 8206, 422 8207, 422 8208, 422 8211, 2504581, 2504591, G01N 3300, G01N 2176

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056912056

ABSTRACT:
Provided is a fluorometric analytical method for detecting chloride ion in a sample by quenching of fluorescence of a fluorescent dye, the fluorescent dye being one of 3,6-bis(dimethylamino)acridine and a derivative thereof of the formulae ##STR1## wherein R is alkyl having 1 to 30 carbon atoms, and X.sup.- is a halogen ion.

REFERENCES:
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Kao et al. (abstract CA # 117:2 2691) From Proc. SPIE-Int. Soc. Opt. Eng. vol. 1648, 1992, pp. 194-201.
Analytical Chemistry, Edmund Urbano et al., Mar. 1984, vol. 56, No. 3, pp. 427-429, "Optical Sensor for Continuous Detrmination of Halides".
Analytical Chemistry, vol. 62, No. 18, Sep. 15, 1990, pp. 2054-2055, "Ion-Selective Optrode Using Hexadecyl-Acridine Orange Attached on Poly(vinyl chloride) Membrane".
Journal of the Chemical Society of London, vol. VII, pp. 174-184, "Stokes on a Certain Reaction of Quinine", 1869.
Analytical Chemistry, vol. 57, No. 13, Nov. 1985, pp. 2556-2561, O. S. Wolfbeis et al., "Fiber Optical Fluorosensor for Determination of Halothane and/or Oxygen".
Analytical Methods and Instrumentation, vol. 1, No. 1,60-72 (1993), H. M. Widmer, "Ion-Selective Electrodes and Ion Optodes".

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