Fluorogypsum waste solidification material

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Alkaline earth metal

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Details

106786, 106775, 210751, 423172, 423485, 423555, C01F 1146, C04B 106

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active

049352113

ABSTRACT:
A process, and the product produced thereby, for the preparation of a waste solidification material from hardened fluorogypsum as a by-product of the manufacture of hydrofluoric acid by reacting fluorospar with sulfuric acid, removing hydrogen fluoride from the reaction product, slurrying the by-product with water, placing the slurried by-product fluorogypsum in settlement ponds until the fluorogypsum hardens, the hardened fluorogypsum having a pH of about 3 to about 5, including heating the hardened fluorogypsum to evaporate substantially all water physically mixed with the fluorogypsum and further heating the fluorogypsum to reduce the water chemically bound to calcium sulfate in the fluorogypsum to from about 0.5% to about 9% by weight.

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