Fluoroalkylated amphiphilic ligands and their metallic complexes

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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546 8, 546258, C07F 1702, C07F 1700, C07F 1500, C07D40104

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active

053996941

ABSTRACT:
Fluoroalkylated amphiphilic ligands of bipyridine (I) that form complexes with platinum and palladium are disclosed. ##STR1## wherein R.sup.1 and R.sup.2 are independently a hydrogen atom, or a fluoroalkylated or hydrocarbon chain, provided at least one of R.sup.1 and R.sup.2 is a fluoroalkylated chain, and W represents a methylene, ester, ether, carbonyl or amide group.

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Garelli N., et al. Synthesis of new amphiphilic perfluoroalkylated bipyridines. J. Org. Chem. 57:3046-3051 (1992).
Teicher, B. A., et al. Effect of various oxygenation conditions and Fluosol-DA on cancer chemotherapeutic agents. Chem. Abstract 109: 163089u vol. 109, p. 31 (1988).
Garelli et al., Inorg. Chim. Acta., 194(2), 247-53 (1992).

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