Fluoroaliphatic-thio,-sulfinyl, or sulfonyl substituted bicycloa

Compositions: coating or plastic – Coating or plastic compositions – O-containing organic compound

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Details

10628724, 1062872, 106208, 106181, 106213, 524 96, 544108, 549237, 549463, 562502, 564154, C09K 300, C08K 535

Patent

active

045156409

ABSTRACT:
Fluoroaliphatic-thio,-sulfinyl and -sulfonyl substituted bicycloaliphatic amic acid amine salts of the formula: ##STR1## where R.sub.f is perfluoroalkyl, R' is alkylene optionally interrupted by --O--, --S-- or ##STR2## where R.sub.a is hydrogen or alkyl, Y is lower alkylene or --O--, n is 0-2, R.sub.1 and R.sub.2 are independently hydrogen, lower alkyl, hydroxy lower alkyl or together with the nitrogen to which they are attached, represented morpholino, R.sub.3, R.sub.4 and R.sub.5 are independently hydrogen, lower alkyl, or hydroxy lower alkyl, R.sub.6 is lower alkyl, carboxy lower alkyl, sulfo lower alkyl, hydroxy lower alkyl, benzyl or together with R.sub.5 and the nitrogen to which they are attached represent morpholino, and R is hydrogen or methyl are provided. These salts applied in the form of aqueous solutions, dispersions or emulsions are useful in rendering cellulosic and natural and synthetic polyamide materials oil and water repellent.

REFERENCES:
patent: 3989725 (1976-11-01), Brace
patent: 4056531 (1977-11-01), Malec
patent: 4082798 (1978-04-01), Brace
patent: 4228096 (1980-10-01), Bozzelli et al.
patent: 4419298 (1983-12-01), Falk et al.

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