Fluoroacrylate ester, polymer thereof, and process of making the

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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560221, 526246, C07C 4320, C07C 4100, C07C 4302

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active

046330232

ABSTRACT:
A fluoroacrylate ester monomer having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are independently selected from the group consisting of saturated aliphatic hydrocarbons having from 1 to about 3 carbon atoms and R.sub.3 is selected from the group consisting of hydrogen and methyl. The monomer has a water-repellent "umbrella" of 3 gem bis trifluoromethyl groups around the acrylate monomer which do not interfere with the acrylate properties. Polymerization of the monomer results in a stable, exceptionally hydrophobic, linear thermoplastic polymer. The invention also includes processes for making the monomer from a diether halide and certain novel intermediates.

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