Fluorine containing polymer having a terminal ester group

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526250, 526254, 526255, C08F 1220

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active

048576190

ABSTRACT:
A fluorine containing polymer having a terminal ester group is prepared from the free radical polymerization of an acyclic ketane acetal with a vinyl monomer component including a fluorine containing vinyl monomer.
The fluorine containing polymer can be utilized to prepare functional oligomers suitable for many uses including film former and additives for coating applications.

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Dunn and Plesch, "The Cationic Polymerization of Ketene Acetals and the Preparation and Characterization of Poly(1,3-Diketones)", Die Makromolekulare Chemie, 175, 2821-2836, (1974).
Bailey et al., "Synthesis of Poly-e-Caprolactone Via a Free Radical Mechanism, Free Radical Ring-Opening Polymerization of 2-Methylene-1,3-Dioxepane", Journal of Polymer Science: Polymer Chemistry Edition, vol. 20, 3021-3030, (1982), copyright 1982 by John Wiley & Sons, Inc.
"Photoinitiated Ring-Opening Polymerization of 2-Methylene-1,3-Dioxepane", Journal of Polymer Science: Polymer Letters Edition, vol. 21, 373-380, (1983), copyright 1983 by John Wiley & Sons, Inc.
Endo, Fukada, Hirota, "Reaction of Cyclic Ketene Acetal and Carbon Disulfide Through Macrozwitterion", Journal of the American Chemical Society, 1984, 106, 4035-4036.
Bailey et al., "Synthesis of Functionally-Terminated Oligomers by Free Radical Ring-Opening Polymerization", J. Macromol. Sci. Chem. Azi (8 & 9), 979-995, (1984) copyright 1984 by Marcel Dekker, Inc.
Bailey et al., "Free Radical Ring-Opening Polymerization of 4,7-Dimethyl-2-Methylene-1,3-Dioxepane and 5,6-Benzo-2-Methylene-1,3-Dioxepane", Macromolecules, 15, 711, (1982).
Bailey, Gapud, "Synthesis of Biodegradable Polyethylene", Am. Chem. Soc., Div. Polymer Chem., Preprints, 25(1), 58, (1984).
Bailey et al., "The Use of Free Radical Ring-Opening Polymerization for the Synthesis of Reactive Oligomers", Am. Chem. Soc., Div. Polymer Chem., Preprints, 25(1), 142, (1984).
Bailey, "Free Radical Ring-Opening Polymerization", Am. Chem. Soc., Div. Polymer Chem., Preprints, 25(1), 210, (1984).

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