Fluorine-containing copolymer and curable composition containing

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526249, 526254, 526255, C08F 1220, C08F 1418

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active

051699150

ABSTRACT:
A fluorine-containing copolymer comprising 20 to 60% by mole of the fluoroolefin unit (1), 5 to 45% by mole of the .beta.-methyl substituted .alpha.-olefin unit (2), 1 to 45% by mole of the unit (3) derived from a monomer having a chemically curable functional group, 1 to 45% by mole of the unit (4) derived from a monomer having ester moieties in the side chains and 0 to 45% by mole of the unit (5) derived from a copolymerizable monomer other than the above monomers, if necessary, 0.1 to 15% by mole of the unit (6) derived from a monomer having carboxyl groups. The copolymer can provide a curable composition alone or with an acrylic polymer. The fluorine-containing copolymer is excellent in solvent-solubility, compatibility with curing agents, additives and other polymers, pigment dispersibility, curing reactivity, dispersibility to water, pot life, film forming ability, coating properties, and the like. The coating film prepared from the copolymer has a high weatherability and is excellent in film properties such as stain resistance, heat-yellowing resistance, dechlorination resistance, optical properties, adhesion to a substrate, mechanical properties, heat resistance, chemical resistance, solvent (gasoline) resistance, water resistance and good appearance of finished products.

REFERENCES:
patent: 3380971 (1968-04-01), Chalmers et al.
patent: 3380974 (1968-04-01), Stilmar
patent: 3445434 (1969-05-01), Stilmar
patent: 3579474 (1971-05-01), Ro
patent: 3859259 (1975-01-01), Harrell et al.
patent: 4701508 (1987-10-01), Homma et al.
patent: 4751114 (1988-06-01), Homma et al.
"Emulsion Polymerization of Tetrafluoroethylene and Isobutylene" by Coker, Jour. of Polymer Science No. 11 vol. 13, 2473-2489 Nov. 1975.

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