Fluorination of superconducting YBa.sub.2 Cu.sub.3 O.sub.7-x pow

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

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505742, 505780, 252521, 423593, H01L 3912

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active

050811037

ABSTRACT:
A method of incorporating fluorine into the YBa.sub.2 Cu.sub.3 O.sub.7-x system by annealing YBa.sub.2 Cu.sub.3 O.sub.7-x powder in a fluorine-containing gas, especially NF.sub.2 gas. The YBa.sub.2 Cu.sub.3 O.sub.7-x material is annealed in the fluorine-containing gas (either pure NF.sub.3 or NF.sub.3 /O.sub.2 blend of F.sub.2 /N.sub.2 blend) at a temperature which allows sufficient reactivity with the fluorine gas while maintaining the system well below temperatures at which oxygen incorporation is observed to take place in the normal YBa.sub.2 Cu.sub.3 O.sub.7-x system.

REFERENCES:
patent: 4916116 (1990-04-01), Yamazaki
LaGraff et al, "Magnetic and Structural Properties of YBa.sub.2 Cu.sub.3 O.sub.7-x F.sub.y as prepared by a NF.sub.3 gas anneal", Phys. Rev. B. vol. 39 No. 1, Jan. 1989 pp. 347-355.

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