Fluorination of articles molded from elastomers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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5253264, 5253293, 5253303, 5253312, 5253317, 5253328, 5253329, 5253331, 5253332, 5253341, C08F 822

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active

052740498

ABSTRACT:
A method of reducing the static and dynamic coefficients of friction and improving the wear life of thermoset elastomeric articles is disclosed. The elastomeric articles are fluorinated in the presence of a hydrogen fluoride scavenger under conditions sufficient to reduce said friction coefficient and improve said wear life, without promoting degradation of the tensile properties of the articles.

REFERENCES:
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patent: 3992221 (1976-11-01), Homsy et al.
patent: 4020223 (1977-04-01), Dixon
patent: 4076916 (1978-02-01), Lagow
patent: 4144374 (1979-03-01), Lagow et al.
patent: 4404256 (1983-09-01), Anand et al.
patent: 4593050 (1986-06-01), Cohen et al.
patent: 4621107 (1986-11-01), Lagow et al.
patent: 4900793 (1990-02-01), Lagow et al.
"The Direct Fluorination of Hydrocarbon Polymers" by Otsuka and Lagow, Journal of Fluorine Chemistry (1974) 371-380.
"The Controlled Reaction of Hydrocarbon Polymers with Elemental Fluorine" by Lagow and Margrave, Polymer Letters Ed. vol. 12, pp. 177-184 (1974).

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