Fluorination of articles molded from elastomers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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524525, 524571, 524575, 524590, 524601, 524606, 5253317, 5253328, 5253329, 5253331, 525356, 525410, 525437, 525448, 525450, 525451, 525453, C08F 822

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052141020

ABSTRACT:
A method of producing fluorinated elastomeric articles having reduced coefficients of friction, improved wear life and improved resistance to fluid permeability. A thermoplastic elastomeric article is exposed to gaseous fluorine in a reactor vessel under reaction conditions sufficient to create a fluorinated material on the external portions of the elastomeric article, which fluorinated material extends inwardly into the matrix of the article, without promoting degradation of the tensile properties of the article.

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patent: 4900793 (1990-02-01), Lagow et al.
"The Direct Fluorination of Hydrocarbon Polymers" by Otsuka and Lagow, Journal of Fluorine Chemistry (1974) 371-380.
"The Controlled Reaction of Hydrocarbon Polymers with Elemental Fluorine" by Lagow and Margrave, Polymer Letters Ed. vol. 12, pp. 177-184 (1974).

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