Fluorinated copolymers for microlithography

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S242000, C526S243000, C526S282000, C430S270100

Reexamination Certificate

active

07019092

ABSTRACT:
Fluorinated copolymers useful in photoresist compositions and associated processes for microlithography are described. These copolymers are comprised of a fluoroalcohol or protected fluoroalcohol functional group which simultaneously imparts high ultraviolet (UV) transparency and developability in basic media to these materials and a repeat unit derived from an acrylate monomer containing a fluoroalkyl group or a hydroxyl substituted alkyl group. The materials of this invention have high UV transparency, particularly at 193 and 157 nm, which makes them highly useful for lithography at these short wavelengths.

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K. Patterson, et al., Advances in Resist Technology and Processing XVII, Proc. of SPIE, Mar., 2000, pp. 365-374, vol. 3999.
Patent Abstract, AN 1987-268006, JP 62186907, Agency of Ind. Sci. & Technology, Sep. 22, 1993.

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