Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge
Patent
1975-12-22
1977-02-15
Sebastian, Leland A.
Chemistry: electrical and wave energy
Processes and products
Electrostatic field or electrical discharge
260632R, 260635R, B01J 110, C07C 3134
Patent
active
040081397
ABSTRACT:
1,1,4,4-Tetrakis(trifluoromethyl)butan-1,4-diol and 1,1-bis (trifluoromethyl)propanol-1 are prepared by reacting gaseous hexafluoroacetone and ethane in a transparent container in the presence of sunlight. The diol is a crystalline solid and the propanol-1 is a liquid. The diol is useful as a monomer in the field of polymer chemistry. That is, polymers such as polyurethans and polyesters which find many applications in the chemical industry can be made by reacting the proper material with the diol of this invention. The propanol-1 is useful as a plasticizer for polyurethans and other plastics.
REFERENCES:
gordon et al., International Journal of Chemical Kinetics, vol. VII, pp. 15 o 22 (1975).
Howard et al., J. Am. Chem. Soc., vol. 89, pp. 1422 to 1430 (1967).
Gordon Alvin S.
Johnson Joseph H.
Norris William P.
Miller Roy
Pohl L. E. K.
Sciascia R. S.
Sebastian Leland A.
The United States of America as represented by the Secretary of
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