Fluorinated cation exchange membrane and electrolytic soda...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Ion-exchange polymer or process of preparing

Reexamination Certificate

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Details

C521S029000, C521S031000, C204S296000, C205S344000

Reexamination Certificate

active

06984669

ABSTRACT:
The present invention provides a fluorinated cation exchange membrane comprising at least two layers, a first layer made of a fluoropolymer having sulfonic acid groups and a second layer made of a fluoropolymer having carboxylic acid groups on the cathode side thereof, wherein when an electrolytic soda process is conducted using the cation exchange membrane as a diaphragm between an anode compartment and a cathode compartment, the water transport number through the cation exchange membrane is at least 4.8 mol/F (F: Faraday) under operating conditions such that the brine concentration in the anode compartment is 200 g/L, the sodium hydroxide concentration in the cathode compartment is 32 mass %, the current density is 5 kA/m2, and the temperature is 90° C. The fluorinated cation exchange membrane of the present invention gives an excellent effect such that a uniform catholyte concentration can be maintained even when installed in an electrolytic cell having no special circulating means.

REFERENCES:
patent: 4544471 (1985-10-01), Silva et al.
patent: 4587274 (1986-05-01), Nakahara et al.
patent: 4626553 (1986-12-01), Hane et al.
patent: 5716504 (1998-02-01), Saito et al.
patent: 0 045 603 (1982-02-01), None
patent: 0 192 261 (1986-08-01), None
patent: 5-125579 (1993-05-01), None
patent: 6-330369 (1994-11-01), None
patent: 2000-1794 (2000-01-01), None

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