Fluorinated carbons and methods of manufacture

Chemistry of inorganic compounds – Carbon or compound thereof – Oxygen containing

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148 4, 204294, 423439, 429218, 502181, 502416, C01B 3100

Patent

active

049081985

ABSTRACT:
Discontinuities, edge sites and grain boundaries in carbons, the primary locations of instabilities for oxidative corrosion and degradation, are prepared by preoxidation to form carbon-oxides followed by highly selective and relatively mild fluorination to specifically substitute carbon-oxygen functionality with stable carbon-fluorine groups. The novel fluorinated carbons have enhanced chemical and/or electrochemical stabilities to corrosion, improved hydrophobicity, lubricating properties, etc.

REFERENCES:
patent: 2709186 (1955-05-01), Farlow et al.
patent: 3340081 (1967-09-01), Teter
patent: 3674432 (1972-07-01), Margrave et al.
patent: 4105836 (1978-08-01), Almerini
patent: 4119655 (1978-10-01), Hulme
patent: 4316782 (1982-02-01), Foller et al.
Hackh's Chemical Dictionary, 4th Ed., Julius Grant, ed. McGraw-Hill Book Co. 1969, pp. 15, 147, 378, 625.
"Fluorination of Carbon Black", Watanabe et al., Carbon, vol. 17, p. 359, 1979.
Peter C. Foller et al., Electrochemical Generation of High-Concentration Ozone for Waste Treatment, CEP, Mar. 1985, 49-51.

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