Fluorinated butene derivatives and methods for their preparation

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568661, 568663, 568683, 568685, 568 58, 568 35, 568 32, 560219, 564226, 520136, C07C 4105, C07C 4315, C07C 43166

Patent

active

049028359

ABSTRACT:
New chemical reactions of 1,1,2-trifluoro-1,3-butadiene provide simple access to a series of new fluorinated alkene derivatives. These derivatives provide a simple, general methodology for the stereocontrolled preparation of 2-fluoro-2-alkenoate esters and related monofluoroalkene derivatives which include fluoro analogs of known insecticides, pheromones or pharmaceuticals. A new method for the preparation of 1,1,2-trifluoro-1,3-butadiene is also provided.

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